MilliporeSigma
All Photos(1)

Documents

726621

Sigma-Aldrich

(R)-(+)-α-Methylbenzylamine

ChiPros®, produced by BASF, ≥99.0%

Sign Into View Organizational & Contract Pricing

Synonym(s):
(R)-(+)-1-Phenylethylamine
Linear Formula:
C6H5CH(CH3)NH2
CAS Number:
Molecular Weight:
121.18
Beilstein/REAXYS Number:
2410916
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

produced by BASF

Quality Level

vapor pressure

0.5 mmHg ( 20 °C)

assay

≥99.0% (GC)
≥99.0%

form

liquid

optical purity

enantiomeric excess: ≥98.0%

refractive index

n20/D 1.526 (lit.)

bp

187-189 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

SMILES string

C[C@@H](N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

InChI key

RQEUFEKYXDPUSK-SSDOTTSWSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
7788011554177879
(R)-(+)-α-Methylbenzylamine ChiPros®, produced by BASF, ≥99.0%

726621

(R)-(+)-α-Methylbenzylamine

(R)-(+)-α-Methylbenzylamine purum, ≥98.0% (sum of enantiomers, GC)

77880

(R)-(+)-α-Methylbenzylamine

(R)-(+)-α-Methylbenzylamine 98%

115541

(R)-(+)-α-Methylbenzylamine

(R)-(+)-α-Methylbenzylamine for chiral derivatization, LiChropur™, ≥99.0%

77879

(R)-(+)-α-Methylbenzylamine

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

-

form

liquid

density

0.952 g/mL at 20 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

refractive index

n20/D 1.526 (lit.)

refractive index

n20/D 1.526 (lit.), n20/D 1.528

refractive index

n20/D 1.526 (lit.)

refractive index

n20/D 1.526 (lit.), n20/D 1.528

bp

187-189 °C (lit.)

bp

187-189 °C (lit.)

bp

187-189 °C (lit.)

bp

187-189 °C (lit.)

General description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

Application

(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
  • (S)-α-amino phosphonates
  • N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine
  • R-α-aminonitriles

Legal Information

ChiPros is a registered trademark of BASF SE

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Customers Also Viewed

Slide 1 of 3

1 of 3

L-(+)-Tartaric acid ACS reagent, ≥99.5%

Sigma-Aldrich

251380

L-(+)-Tartaric acid

Chloroform contains 100-200 ppm amylenes as stabilizer, ≥99.5%

Sigma-Aldrich

C2432

Chloroform

Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
Karim Engelmark Cassimjee et al.
Organic & biomolecular chemistry, 10(28), 5466-5470 (2012-06-13)
For biocatalytic production of pharmaceutically important chiral amines the ω-transaminase enzymes have proven useful. Engineering of these enzymes has to some extent been accomplished by rational design, but mostly by directed evolution. By use of a homology model a key
Sachin R Chaudhari et al.
Organic & biomolecular chemistry, 10(31), 6410-6419 (2012-06-28)
The three-component chiral derivatization protocols have been developed for (1)H, (13)C and (19)F NMR spectroscopic discrimination of chiral diacids by their coordination and self-assembly with optically active (R)-α-methylbenzylamine and 2-formylphenylboronic acid or 3-fluoro-2-formylmethylboronic acid. These protocols yield a mixture of

Articles

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service