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759406

Sigma-Aldrich

Triethylene glycol dimethacrylate

contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99%

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Linear Formula:
CH2=C(CH3)COO(CH2CH2O)3COC(CH3)=CH2
CAS Number:
Molecular Weight:
286.32
Beilstein/REAXYS Number:
1797351
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99%

form

liquid

contains

200 ppm monomethyl ether hydroquinone as inhibitor

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

refractive index

n20/D 1.461 (lit.)
n/D 1.4613

bp

170-172 °C/5 mmHg (lit.)

density

1.092 g/mL at 25 °C (lit.)
1.074 g/mL

polymer architecture

shape: linear
functionality: homobifunctional

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C

InChI

1S/C14H22O6/c1-11(2)13(15)19-9-7-17-5-6-18-8-10-20-14(16)12(3)4/h1,3,5-10H2,2,4H3

InChI key

HWSSEYVMGDIFMH-UHFFFAOYSA-N

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This Item
261548409510437468
vibrant-m

759406

Triethylene glycol dimethacrylate

vibrant-m

261548

Triethylene glycol dimethacrylate

form

liquid

form

liquid

form

liquid

form

liquid

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

density

1.092 g/mL at 25 °C (lit.), 1.074 g/mL

density

1.092 g/mL at 25 °C (lit.)

density

1.099 g/mL at 25 °C

density

1.11 g/mL at 25 °C

General description

Triethylene glycol dimethacrylate is used as a cross-linking agent in the synthesis of poly (methacrylic acid-g-ethylene glycol ) hydrogels which shows large changes in swelling due to changes in pH, temperature and solvent composition. They are also used as a divinylic methacrylic monomer which are widely used to form copolymers with divinylbenzene (DVB) and glycidyl methacrylate (GMA) or hydroxyethyl methacrylate (HEMA) comonomers.

Application

  • Used as a diluent comonomer in dimethacrylate based dental composites.
  • Used as a branching agent in the atom transfer radical polymerization (ATRP) of styrene.

Features and Benefits

Lower viscosity compared to other dimethacrylate monomers enabling higher amounts of filler to be incorporated in dental composites. Non-toxic and can be rapidly polymerized in the presence of oxygen and water.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

332.6 °F - closed cup

flash_point_c

167 °C - closed cup


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Customers Also Viewed

I Sideridou et al.
Biomaterials, 23(8), 1819-1829 (2002-04-13)
In this work the room-temperature photopolymerization of Bis-GMA, Bis-EMA, urethane dimethacrylate (UDMA) and triethylene glycol dimethacrylate (TEGDMA) induced by camphoroquinone/N,N-dimethylaminoethyl methacrylate, as photo-initiator system, was followed by FT-IR. The results obtained were then fitted by a non-linear least square method
Controlled release by using poly (methacrylic acid-g-ethylene glycol) hydrogels
Peppas, N. A., & Klier, J.
Journal of Controlled Release : Official Journal of the Controlled Release Society, 16(1), 203-214 (1991)
Mono-or narrow disperse poly (methacrylate-co-divinylbenzene) microspheres by precipitation polymerization
Li, W. H., & Stover, H. D.
Journal of Polymer Science Part A: Polymer Chemistry, 37(15), 2899-2907 (1999)
Development of branching in atom transfer radical copolymerization of styrene with triethylene glycol dimethacrylate
Yang, H. J., Jiang, B. B., Huang, W. Y., Zhang, D. L., Kong, L. Z., Chen, J. H., & Yang, Y.
Macromolecules, 42(16), 5976-5982 (2009)
Geum-Jun Han et al.
The journal of adhesive dentistry, 14(5), 461-469 (2012-06-23)
To evaluate the effect of applied power on dental ceramic bonding of composite resin using nonthermal atmospheric pressure plasma (APP). A pencil-type APP torch was used to modify the surface chemical composition and hydrophilicity of dental ceramic and to improve

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