Skip to Content
MilliporeSigma
All Photos(1)

Documents

76050

Sigma-Aldrich

Palladium(II) chloride

anhydrous, 60% Pd basis

Sign Into View Organizational & Contract Pricing
All Photos(1)
Synonym(s):
Dichloropalladium, Palladium dichloride, Palladous chloride
Empirical Formula (Hill Notation):
Cl2Pd
CAS Number:
7647-10-1
Molecular Weight:
177.33
EC Number:
231-596-2
MDL number:
MFCD00003558
UNSPSC Code:
12352300
PubChem Substance ID:
57652613
NACRES:
NA.22

Quality Level

200

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

concentration

60% Pd

mp

678-680 °C (lit.)

density

4 g/mL at 25 °C (lit.)

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Palladium(II) chloride can be used to catalyze:
  • Cross-coupling reactions between terminal alkynes and aryl iodides or bromides under modified Sonogashira-Cassar-Heck conditions.
  • Carbonylation of organic tellurides with carbon monoxide to form corresponding methyl carboxylates.
  • Isomerization of allylic ester in acetic acid.
  • Carbonylation of amines to form isocyanates.

Other Notes

Review

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 8

1 of 8

Palladium(II) iodide ≥99.98% trace metals basis

Sigma-Aldrich

203963

Palladium(II) iodide

Platinum(II) chloride 99.99% trace metals basis

Sigma-Aldrich

482315

Platinum(II) chloride

Platinum(IV) chloride ≥99.9% trace metals basis

Sigma-Aldrich

520640

Platinum(IV) chloride

Palladium(II) nitrate dihydrate ~40% Pd basis

Sigma-Aldrich

76070

Palladium(II) nitrate dihydrate

[Pd(OAc)2]3 reagent grade, 98%

Sigma-Aldrich

205869

[Pd(OAc)2]3

Sodium tetrachloropalladate(II) ≥99.99% trace metals basis

Sigma-Aldrich

379808

Sodium tetrachloropalladate(II)

Chloroplatinic acid hydrate ~38% Pt basis

Sigma-Aldrich

81080

Chloroplatinic acid hydrate

Bis(triphenylphosphine)palladium(II) dichloride

Sigma-Aldrich

741248

Bis(triphenylphosphine)palladium(II) dichloride

Palladium (II)-catalyzed exchange and isomerization reactions. III. Allylic esters isomerization in acetic acid catalyzed by palladium (II) chloride.
Henry P M.
Journal of the American Chemical Society, 94(15), 5200-5206 (1972)
Carbonylation of Amines in the Presence of Palladium (II) Chloride. A New Route to Isocyanates.
Stern E. W and Spector M. L.
The Journal of Organic Chemistry, 31(2), 596-597 (1966)
Palladium (II) Chloride and a (Dipyridin?2?ylmethyl) amine?Derived Palladium (II) Chloride Complex as Highly Efficient Catalysts for the Synthesis of Alkynes in Water or in NMP and of Diynes in the Absence of Reoxidant.
Gil?Molto J and Najera C.
European Journal of Organic Chemistry, 2005(19), 4073-4081 (2005)
R.F. Heck
Accounts of Chemical Research, 12, 146-146 (1979)
Farnaz Jafarpour et al.
The Journal of organic chemistry, 75(9), 3109-3112 (2010-04-14)
An atom-economical phosphane-free palladium-catalyzed direct C-2 arylation of unactivated free NH-pyrroles is devised. This method provides a straightforward route to a wide variety of substituted 2-aryl-1H-pyrroles from readily accessible starting materials. Iodoarenes bearing electron-withdrawing and electron-donating substituents are tolerated under
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service