804975

DTBPF-Pd-G3

• Synonym(s): 1,1′-Bis(di-tert-butylphosphino)ferrocene Pd G3
• Empirical Formula (Hill Notation): C₃₉H₅₇FeNO₃P₂PdS
• Molecular Weight: 844.15
• MDL number: MFCD28009169
• UNSPSC Code: 12352103
• PubChem Substance ID: 329768913
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• feature: generation 3
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• impurities: may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number 762156); may contain 5-10% DTBPF (Aldrich Number 695149); may contain 5-10% pentane
• mp: 87-150 °C (decomposition)
• functional group: phosphine
• InChI: 1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1
• InChI key: AGXLTHQKOWPGBX-UHFFFAOYSA-M

Description

General description

DTBPF-Pd-G-3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF₃, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.

Application

Pd precatalyst for cross-coupling. Buchwald Third Generation Palladium Precatalyst.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable