900621

CyJohnPhos Pd G3

95%

• Synonym(s): (2-Dicyclohexylphosphino-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, CyJohnPhos G3
• Empirical Formula (Hill Notation): C₃₇H₄₄NO₃PPdS
• CAS Number: 2230788-64-2
• Molecular Weight: 720.21
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• form: powder or crystals
• feature: generation 3
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• functional group: phosphine
• SMILES string: O=S(=O)([O-][Pd+2]1([C-]=2C=CC=CC2C=3C=CC=CC3[NH2]1)[P](C=4C=CC=CC4C=5C=CC=CC5)(C6CCCCC6)C7CCCCC7)C
• InChI: InChI=1S/C24H31P.C12H10N.CH4O3S.Pd/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;+2/p-1
• InChI key: NFZUZGPTBAUUOC-UHFFFAOYSA-M

Description

Application

Third generation (G3) Buchwald palladium precatalyst for cross-coupling, demonstrating improved stability and reactivity from previous generations. This same product was formerly listed under RNI00192.

Other Notes

G3 and G4 Buchwald Precatalysts

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable