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About This Item
Empirical Formula (Hill Notation):
C43H38O2P2
Molecular Weight:
648.71
UNSPSC Code:
12161600
Product Name
(S,S,S)-SPIRAP, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Asymmetric synthesis
reagent type: ligand
mp
226-228 °C
functional group
phosphine
SMILES string
CC[C@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2
Application
(S,S,S)-SPIRAP is a chiral C2-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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