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911402

Sigma-Aldrich

(CyPAd-DalPhos)NiCl(otol)

≥95%

Synonym(s):

8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride

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5 G
$282.00

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5 G
$282.00

About This Item

Empirical Formula (Hill Notation):
C35H49ClNiO3P2
CAS Number:
Molecular Weight:
673.86
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22

form:
powder
assay:
≥95%

$282.00


In StockDetails


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assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

193-197 °C

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This Item
16175613431795755
Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

density

1.66 g/mL at 25 °C (lit.)

density

1.531 g/mL at 25 °C (lit.)

density

1.074 g/mL at 25 °C (lit.)

density

1.202 g/mL at 20 °C (lit.)

refractive index

n20/D 1.483 (lit.)

refractive index

n20/D 1.456 (lit.)

refractive index

n20/D 1.546 (lit.)

refractive index

-

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

bp

158 °C (lit.)

bp

87 °C (lit.)

bp

75-76 °C/0.5 mmHg (lit.)

bp

88-90 °C/0.02 mmHg (lit.)

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation

target_organs

Respiratory Tract,Skin

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature
Tassone J P, et al.
ACS Catalysis, 7(9), 6048-6059 (2017)
Preston M MacQueen et al.
Journal of the American Chemical Society, 140(15), 5023-5027 (2018-03-31)
The use of (L)Ni( o-tolyl)Cl precatalysts (L = PAd-DalPhos or CyPAd-DalPhos) enables the C( sp2)-O cross-coupling of primary, secondary, or tertiary aliphatic alcohols with (hetero)aryl electrophiles, including unprecedented examples of such nickel-catalyzed transformations employing (hetero)aryl chlorides, sulfonates, and pivalates. In
Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature
Tassone J P, et al
ACS Catalysis, 7(9), 6048-6059 (2017)

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