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920347

Sigma-Aldrich

Lithium hexafluoroarsenate(V)

anhydrous, 99.9% trace metals basis

Synonym(s):

LiAsF6, Lithium fluoarsenate, Hexafluoroarsenate(V) lithium

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About This Item

Linear Formula:
LiAsF6
CAS Number:
Molecular Weight:
195.85
MDL number:
UNSPSC Code:
12352302
NACRES:
NA.23

grade

anhydrous
battery grade

Quality Level

assay

99.9% trace metals basis

form

powder

impurities

≤100 ppm H2O

mp

240 °C (lit.)

application(s)

battery manufacturing

SMILES string

[Li+].F[As-](F)(F)(F)(F)F

InChI

1S/AsF6.Li/c2-1(3,4,5,6)7;/q-1;+1

InChI key

GTZQZEYBOGZTEO-UHFFFAOYSA-N

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Application

Lithium hexafluoroarsenate(V) can be used for deposition of electrolyte interface layers and creation of low permittivity electrolytes and polymer composite electrolyte films.
The surface chemistry of Li electrodes in ethereal LiAsF6 was tested with new salts for potential battery systems.

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Skull and crossbonesEnvironment

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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The Interplay between Salt Association and the Dielectric Properties of Low Permittivity Electrolytes: The Case of LiPF6 and LiAsF6 in Dimethyl Carbonate.
Self J, et al.
The Journal of Physical Chemistry C, 122(4), 1990-1994 (2018)
Structure, Electrical and Optical Properties of (PVA/LiAsF6) Polymer Composite Electrolyte Films
Varishetty M M , et al
Polym. Eng. Sci., 50, 878-884 (2010)
Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF6 and Cyclic Carbonate Additives.
Ren X, et al.
ACS Energy Letters, 3(1), 14-19 (2018)

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