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ALD00430

Sigma-Aldrich

1-Naphthalenyl ester fluorosulfuric acid

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About This Item

Empirical Formula (Hill Notation):
C10H7FO3S
CAS Number:
133042-64-5
Molecular Weight:
226.22
UNSPSC Code:
12352100
PubChem Substance ID:
329772677
NACRES:
NA.22

description

Fp: >230°F

Quality Level

100

form

liquid

refractive index

n20/D 1.5576

density

1.3674 g/mL at 25 °C

SMILES string

O=S(OC1=CC=CC2=CC=CC=C21)(F)=O

InChI

1S/C10H7FO3S/c11-15(12,13)14-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

GEZWNEDYJCOWLU-UHFFFAOYSA-N

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Application

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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