B1252

Boron trifluoride-methanol solution

14% in methanol

• Synonym(s): BF₃ methanol, BF₃MeOH, Boron Trifluoride - Methanol Complex, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol complex, Borontrifluoride methanol, Trifluoroborane
• Linear Formula: BF₃ · MeOH
• CAS Number: 373-57-9
• Molecular Weight: 99.85
• Beilstein/REAXYS Number: 3611499
• MDL number: MFCD00071635
• UNSPSC Code: 12352104
• PubChem Substance ID: 57653917
• NACRES: NA.23

Properties

• form: liquid
• Quality Level: 200
• reaction suitability: reagent type: catalyst; core: boron
• concentration: 12-16% (titration by NaOH); 14% in methanol
• density: 0.859 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CO.FB(F)F
• InChI: 1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
• InChI key: JBXYCUKPDAAYAS-UHFFFAOYSA-N

Description

General description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Application

Used in the deactylation of acetanilides.It is also used to study the synthesis of amino group containing cyanine dyes of different types and to prepare fatty acid methyl esters.

Packaging

Bottle with screw-cap closure.

Safety Information

• pictograms: GHS02,GHS06,GHS08,GHS05
• signalword: Danger
• hcodes: H225,H301 + H311 + H331,H314,H370,H373
• pcodes: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1
• target_organs: Eyes,Central nervous system, Kidney
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 49.5 °F
• flash_point_c: 9.7 °C
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter