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N32601

Sigma-Aldrich

Norcamphor

98%

Synonym(s):

2-Norbornanone, Bicyclo[2.2.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):
C7H10O
CAS Number:
497-38-1
Molecular Weight:
110.15
Beilstein/REAXYS Number:
1209657
EC Number:
207-846-1
MDL number:
MFCD00074823
UNSPSC Code:
12352100
PubChem Substance ID:
24897635
NACRES:
NA.22

Quality Level

100

assay

98%

form

crystals

bp

168-172 °C (lit.)

mp

93-96 °C (lit.)

SMILES string

O=C1C[C@@H]2CC[C@H]1C2

InChI

1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1

InChI key

KPMKEVXVVHNIEY-RITPCOANSA-N

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Related Categories

pictograms

Flame
GHS02

signalword

Danger

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS8807
MKCS8806
MKCP9920
MKBL6578V
MKBK4414V

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Bicyclo[2.2.1]hept-2-ene 99%

Sigma-Aldrich

N32407

Bicyclo[2.2.1]hept-2-ene

M B Bass et al.
Proteins, 13(1), 26-37 (1992-05-01)
While cytochrome P-450cam catalyzes the hydroxylation of camphor to 5-exo-hydroxycamphor with 100% stereospecificity, norcamphor is hydroxylated by this enzyme yielding 45% 5-exo-, 47% 6-exo-, and 8% 3-exo-hydroxynorcamphor (Atkins, W.M., Sligar, S.G., J. Am. Chem. Soc. 109:3754-3760, 1987). The present study
J R Collins et al.
The Journal of biological chemistry, 263(7), 3164-3170 (1988-03-05)
The hydroxylations of d-camphor, norcamphor, pericyclocamphanone, and 5,5-difluorocamphor by cytochrome P-450cam have been examined using theoretical methods to identify and characterize properties which determine product specificity. Experimental results indicate that each molecule is hydroxylated with quite different regio-specificity when metabolized
P J Loida et al.
The Journal of biological chemistry, 270(10), 5326-5330 (1995-03-10)
The stereoselectivity of cytochrome P450cam hydroxylation has been investigated with the enantiomerically pure substrate analog norcamphor. (1R)- and (1S)-norcamphor (> 92 enantiomeric excess) were characterized in the hydroxylation reaction with cytochrome P450cam with respect to the product profile, steady state
Megan C Thielges et al.
The journal of physical chemistry. A, 115(34), 9714-9723 (2011-06-09)
Progress in the field of 2D IR vibrational spectroscopy has been bolstered by the production of intense mid-IR laser pulses. As higher-energy pulses are employed, a concomitant increase occurs in the likelihood of fifth-order contributions to the 2D IR spectra.
J Contzen et al.
Biochemistry, 37(13), 4317-4324 (1998-04-29)
Step-scan time-resolved Fourier transform infrared spectroscopy with a time resolution of 5 micros was applied to the carbon monoxide complex of cytochrome P-450cam (CYP101) to study the bimolecular ligand-rebinding process after flash photolysis. Spectral changes in the CO ligand stretch
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