8.08352

Triethylamine

for synthesis

• Synonym(s): Triethylamine, N,N-Diethylethanamine, TEA
• Linear Formula: (C₂H₅)₃N
• CAS Number: 121-44-8
• Molecular Weight: 101.19
• MDL number: MFCD00009051
• UNSPSC Code: 12352116
• EC Index Number: 204-469-4
• NACRES: NA.22
• grade: synthesis grade
• assay: ≥99% (GC)
• bp: 90 °C/1013 hPa
• vapor pressure: 72 hPa ( 20 °C)

Properties

• grade: synthesis grade
• Quality Level: 300
• vapor pressure: 72 hPa ( 20 °C)
• assay: ≥99% (GC)
• form: liquid
• autoignition temp.: 215 °C
• potency: 730 mg/kg LD₅₀, oral (Rat)
• expl. lim.: 1.2-9.3 % (v/v)
• dilution: (for synthesis)
• pH: 12.7 (15 °C, 100 g/L in H₂O, IUCLID)

Description

General description

Triethylamine is a volatile organic compound used in several industrial processes such as oxidation, reduction, elimination, substitution, addition, and dehydrohalogenation reactions.

Application

Triethylamine can be used as:

• A catalyst in the Domino ring-opening/recyclization reactions of 1,3-thiazolidinedione, malononitrile, and aromatic aldehydes to synthesize polysubstituted dihydrothiophenes.
• A base to synthesize sulfonamides using primary amines and sulfonylating agents.
• A solvent in the Pd-catalyzed cascade Suzuki-Heck reaction.

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.726 - 0.728
Water (K. F.): ≤ 0.20 %
Identity (IR): passes test

Safety Information

• Pictograms: GHS02,GHS06,GHS05
• signalword: Danger
• hcodes: H225,H302,H311 + H331,H314,H335
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 12.2 °F - closed cup
• flash_point_c: -11 °C - closed cup