00410
Ethyl acetoacetate
puriss. p.a., ≥99.0% (GC)
Synonym(s):
Acetoacetic ester
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About This Item
Linear Formula:
CH3COCH2COOC2H5
CAS Number:
Molecular Weight:
130.14
Beilstein/REAXYS Number:
385838
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39022303
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor density
4.48 (vs air)
Quality Level
vapor pressure
1 mmHg ( 28.5 °C)
grade
puriss. p.a.
assay
≥99.0% (GC)
autoignition temp.
580 °F
expl. lim.
9.5 %
impurities
≤0.5% water
refractive index
n20/D 1.419
bp
181 °C (lit.)
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Application
Ethyl acetoacetate can be used as a reactant in the synthesis of:
It can be also utilized as a reactant in the transesterification and asymmetric hydrogenation reactions to produce valuable products.
- Knoevenagel condensation products by reacting with α-alkylideneacetoacetate and aliphatic, aromatic, heteroaromatic aldehydes.
- Michael adducts, via Michael addition reaction with chalcones and azachalcones in the presence of a base catalyst.
- Substituted nicotinic acid derivatives by treating with α, β-unsaturated oximes via Michael addition followed by ring closure reaction.
It can be also utilized as a reactant in the transesterification and asymmetric hydrogenation reactions to produce valuable products.
Storage Class
10 - Combustible liquids
wgk_germany
WGK 1
flash_point_f
164.3 °F - closed cup
flash_point_c
73.5 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Customers Also Viewed
Knoevenagel condensation reaction between benzaldehyde and ethyl acetoacetate in microreactor and membrane microreactor
Lau WN, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 115(1-2), 156-163 (2008)
Michael addition of ethyl acetoacetate to α,β -unsaturated oximes in the presence of FeCl3: a novel synthetic route to substituted nicotinic acid derivatives
Chibiryaev AM, et al.
Tetrahedron Letters, 41(41), 8011-8013 (2000)
Mechanochemical Michael reactions of chalcones and azachalcones with ethyl acetoacetate catalyzed by K2CO3 under solvent-free conditions
Zhang Ze, et al.
Chemistry Letters (Jpn), 33(2), 168-169 (2004)
Boric acid: an efficient and environmentally benign catalyst for transesterification of ethyl acetoacetate
Kondaiah GCM, et al.
Tetrahedron Letters, 49(1), 106-109 (2008)
Enantioselective catalytic asymmetric hydrogenation of ethyl acetoacetate in room temperature ionic liquids
Berthod M, et al.
Tetrahedron Asymmetry, 15(14), 2219-2221 (2004)
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