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07672

Sigma-Aldrich

N,N-Diethyl-p-phenylenediamine sulfate salt

≥98.0% (T)

Synonym(s):

4-Amino-N,N-diethylaniline sulfate salt

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About This Item

Linear Formula:
(C2H5)2NC6H4NH2 · H2SO4
CAS Number:
6283-63-2
Molecular Weight:
262.33
Beilstein/REAXYS Number:
4219768
EC Number:
228-500-6
MDL number:
MFCD00012993
UNSPSC Code:
12352100
PubChem Substance ID:
329748503
NACRES:
NA.22

Quality Level

200

assay

≥98.0% (T)

form

solid

mp

184-186 °C (lit.)
184-187 °C

functional group

amine

SMILES string

OS(O)(=O)=O.CCN(CC)c1ccc(N)cc1

InChI

1S/C10H16N2.H2O4S/c1-3-12(4-2)10-7-5-9(11)6-8-10;1-5(2,3)4/h5-8H,3-4,11H2,1-2H3;(H2,1,2,3,4)

InChI key

AYLDJQABCMPYEN-UHFFFAOYSA-N

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Application

N,N-Diethyl-p-phenylenediamine sulfate salt has been used to prepare N,N-diethyl-p-phenylenediamine (DPD) solution, which is commonly used as a chromogenic indicator for the determination of free and total chlorine by titrimetric, colorimetric and spectroscopic methods.{50

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF3875V
WXBF4652V
WXBF2525V
WXBF4293V
WXBF3060V

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Improvements in the N, N-diethyl-p-phenylenediamine method for the determination of free and combined residual chlorine through the use of FIA.
Gordon G, et al.
Talanta, 38(2), 145-149 (1991)
An improved N, N?-diethyl-p-phenylenediamine (DPD) method for the determination of free chlorine based on multiple wavelength detection.
Moberg L & Karlberg B
Analytica Chimica Acta, 407(1-2), 127-133 (2000)
Allergic contact dermatitis in a photographer.
A Aguirre et al.
Contact dermatitis, 27(5), 340-341 (1992-11-01)
Masoumeh Hasani et al.
Journal of hazardous materials, 157(1), 161-169 (2008-02-15)
A multicomponent analysis method based on principal component analysis-artificial neural network models (PC-ANN) is proposed for the determination of phenolic compounds. The method relies on the oxidative coupling of phenols (phenol, 2 chlorophenol, 3-chlorophenol and 4-chlorophenol) to N,N-diethyl-p-phenylenediamine in the
Jessica A Kershaw et al.
Analytical and bioanalytical chemistry, 379(4), 707-713 (2004-06-04)
The effect of Cu(II) on the determination of homocysteine via its electrochemically initiated reaction with N, N-diethyl-p-phenylenediamine is examined. The presence of copper inhibited the detection process for homocysteine owing to a complexation reaction occurring. This provided an indirect route
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