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11536

Sigma-Aldrich

Lead(II,IV) oxide

≥96%

Synonym(s):

Minium, Red lead oxide, Trilead tetraoxide

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About This Item

Linear Formula:
Pb3O4
CAS Number:
1314-41-6
Molecular Weight:
685.60
EC Number:
215-235-6
MDL number:
MFCD00078491
UNSPSC Code:
12161600
PubChem Substance ID:
57646927
NACRES:
NA.22

vapor pressure

10 mmHg ( 0 °C)

Quality Level

100

assay

≥96%

form

solid

reaction suitability

core: lead
reagent type: catalyst

impurities

≤0.1% in HNO3/H2O2 insoluble matter

anion traces

chloride (Cl-): ≤100 mg/kg

SMILES string

O1[PbH2]O[Pb]12O[PbH2]O2

InChI

1S/4O.3Pb

InChI key

XMFOQHDPRMAJNU-UHFFFAOYSA-N

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General description

Lead(II,IV) oxide is a red pigment commonly used as an anti-corrosive pigment in protective coatings and as electrodes in batteries. In addition, it is also used as a catalyst for the Diels-Alder cycloaddition and as an oxidant for the generation of quinones from hydroquinones.

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Ox. Sol. 2 - Repr. 1A - STOT RE 1

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK3473
BCCL0045
BCCJ1911
BCCJ4836
BCCG9363

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Electrochemical Perforance and Synthesis of Nanostructured Lead Oxide
Wang H
Modern applied science, 4(4), 116-116 (2010)
Synthesis of Six-Membered Functionalized Carbocyclic Compounds by One-Pot Reaction of Hydroquinone Derivatives and Dienes
Cai GR, et al.
Synthetic Communications, 41(20), 3016-3025 (2011)
Yangen Zhou et al.
Inorganic chemistry, 51(23), 12594-12596 (2012-11-13)
Pb(3)O(4) could react with organic dyes in aqueous solution under visible light irradiation, in which Pb(3)O(4) was transformed into Pb(3)(CO(3))(2)(OH)(2) along with oxidation of the organic dyes. Cu(2+) has considerable effect on the reaction. In the presence of Cu(2+), MO
Guo-zhen Lin et al.
Clinica chimica acta; international journal of clinical chemistry, 413(13-14), 1156-1159 (2012-05-09)
Traditional medicines or ethnic remedies, such as Ayurvedic drug of India, have been reported in numerous cases to be one of the main exposure risks for severe lead poisoning. We describe the poisoning of 2 young children from a Chinese
A Fischbein et al.
JAMA, 247(14), 2007-2009 (1982-04-09)
A case of lead poisoning in a female art conservator is reported. The patient had experienced excessive lead exposure while restoring an antique Peruvian tapestry from the Chancay period (1000 to 1500 AD) using a powdered pigment (cinnabar), which had
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