13404

Sodium aluminate

technical

• Synonym(s): Aluminum sodium oxide, Sodium aluminum oxide
• CAS Number: 11138-49-1
• EC Number: 234-391-6
• MDL number: MFCD00085355
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• grade: technical
• Quality Level: 100
• form: powder
• reaction suitability: core: aluminum; reagent type: catalyst
• impurities: ≤0.05% Fe (as Fe₂O₃)
• cation traces: Al (Al₂O₃): 50-56%; Na (as Na₂O): 37-45%
• SMILES string: [Na+].O=[Al-]=O
• InChI: 1S/Al.Na.2O/q-1;+1;;
• InChI key: IYJYQHRNMMNLRH-UHFFFAOYSA-N

Description

General description

Sodium aluminate is used in the synthesis of industrial catalyst mesoporous alumina and various aluminum trihydroxide polymorphs.

Application

Sodium aluminate can be used as a catalyst:

• In the transesterification of glycerol with dimethyl carbonate to synthesize glycerol carbonate.
• In the isomerization of D-glucose into D-fructose.
• To synthesize biodiesel from Jatropha oil via transesterification.
• To convert alcohols into the corresponding unsymmetrical carbonate esters via carboxymethylation by using dimethyl carbonate.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H290,H314
• pcodes: P234 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Met. Corr. 1 - Skin Corr. 1A
• supp_hazards: EUH071
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges