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14765

Sigma-Aldrich

Thallium(I) acetate

purum, ≥97.0%

Synonym(s):

TlOAc, Acetic acid thallium(I) salt

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About This Item

Linear Formula:
CH3COOTl
CAS Number:
563-68-8
Molecular Weight:
263.43
Beilstein/REAXYS Number:
3693914
EC Number:
209-257-5
MDL number:
MFCD00013045
UNSPSC Code:
12161600
PubChem Substance ID:
57647193
NACRES:
NA.22

grade

purum

Quality Level

200

assay

≥97.0%

form

solid

reaction suitability

core: thallium
reagent type: catalyst

SMILES string

CC(=O)O[Tl]

InChI

1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

HQOJMTATBXYHNR-UHFFFAOYSA-M

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General description

Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.

Application

  • Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL9073
BCCK0233
BCCH8281
BCCG5515
BCCG4983

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The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
R Barroso-Moguel et al.
Archives of medical research, 23(3), 129-133 (1992-01-01)
An i.p. injection of a solution of thallium acetate in deionized water at a dose of 32 mg/kg, in 24-h-old rats, produces morphological and biochemical alterations in both cartilaginous and osseous tissues. From the beginning, there are alterations in the
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