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Chloride ionophore I

Selectophore

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Synonym(s):
meso-Tetraphenylporphyrin manganese(III)-chloride complex
Empirical Formula (Hill Notation):
C44H28ClMnN4
CAS Number:
Molecular Weight:
703.11
Beilstein/REAXYS Number:
5699425
MDL number:
PubChem Substance ID:
NACRES:
NB.61

grade

for ion-selective electrodes

Quality Level

product line

Selectophore

SMILES string

Cl[Mn]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChI key

MIUMWNDEIWVIEG-YKKPBKTHSA-M

General description

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application

Selected application examples
Tetraphenylporphyrin manganese (III) chloride complex generally finds application in determining histidine in aqueous solutions by resonance light scattering technique.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Chloride ionophore used in a cellulose acetate membrane electrode

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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M.J. Cha et al.
Analytica Chimica Acta, 315, 311-311 (1995)
Susan C Andrew et al.
Microorganisms, 9(1) (2021-01-21)
Prokaryotic communities coordinate quorum behaviour in response to external stimuli to control fundamental processes including inter-bacterial communication. The obligate intracellular bacterial pathogen Chlamydia adopts two developmental forms, invasive elementary bodies (EBs) and replicative reticulate bodies (RBs), which reside within a
A novel histidine assay using tetraphenylporphyrin manganese (III) chloride as a molecular recognition probe by resonance light scattering technique.
Chen, Zhanguang, et al.
Analytica Chimica Acta, 570, 109-115 (2006)
Alicia Hauke et al.
Biosensors, 10(9) (2020-09-17)
Analysis of sweat chloride levels in cystic fibrosis (CF) patients is essential not only for diagnosis but also for the monitoring of therapeutic responses to new drugs, such as cystic fibrosis transmembrane conductance regulator (CFTR) modulators and potentiators. Using iontophoresis
J Krzystek et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(6), 1113-1127 (2002-05-08)
High-field and -frequency electron paramagnetic resonance (HFEPR) spectroscopy has been used to study three complexes of high spin Manganese(III), 3d4, S = 2. The complexes studied were tetraphenylporphyrinatomanganese(III) chloride (MnTPPCI), phthalocyanatomanganese(III) chloride (MnPcCl), and (8,12-diethyl-2,3,7,13,17,18-hexamethylcorrolato)manganese(III) (MnCor). We demonstrate the ability

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