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74564

Supelco

Trifluoroacetic acid

analytical standard

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Synonym(s):
TFA
Linear Formula:
CF3COOH
CAS Number:
Molecular Weight:
114.02
Beilstein/REAXYS Number:
742035
EC Number:
MDL number:
PubChem Substance ID:

grade

analytical standard

Quality Level

vapor density

3.9 (vs air)

vapor pressure

97.5 mmHg ( 20 °C)

assay

≥99.0% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

impurities

≤0.05% water

refractive index

n20/D 1.3 (lit.)

bp

72.4 °C (lit.)

mp

−15.4 °C (lit.)

solubility

H2O: soluble

density

1.489 g/mL at 20 °C (lit.)

application(s)

environmental

format

neat

SMILES string

OC(C(F)(F)F)=O

InChI

1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)

InChI key

DTQVDTLACAAQTR-UHFFFAOYSA-N

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This Item
91707T6508TX1275
Trifluoroacetic acid analytical standard

74564

Trifluoroacetic acid

Trifluoroacetic acid puriss. p.a., suitable for HPLC, ≥99.0% (GC)

91707

Trifluoroacetic acid

Trifluoroacetic acid ReagentPlus®, 99%

T6508

Trifluoroacetic acid

Trifluoroacetic acid Meets Reagent Specifications for testing USP/NF monographs

TX1275

Trifluoroacetic acid

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, LC/MS: suitable

technique(s)

-

technique(s)

-

format

neat

format

-

format

-

format

-

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

grade

analytical standard

grade

-

grade

-

grade

-

assay

≥99.0% (GC)

assay

≥99.0% (GC)

assay

99%

assay

≥99.5%

General description

Trifluoroacetic acid is a phytotoxic compound belonging to the class of perfluorinated acids (PFAs). It is an environmental contaminant, which contributes to the organo-fluorine burden in surface and ground waters.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Trifluoroacetic acid may be used as a modifier in high performance liquid chromatography mobile phase for protein and peptide separation due to its properties like chromatographic selectivity, high volatility and low ultraviolet light cut-off.
Trifluoroacetic acid may be used as an analytical reference standard for the determination of the analyte in water matrices using high-performance liquid chromatography coupled to tandem mass spectrometry.
Trifluoroacetic acid may be used as a modifier in high performance liquid chromatography mobile phase for protein and peptide separation due to its properties like chromatographic selectivity, high volatility and low ultraviolet light cut-off.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 2

flash_point_f

212.0 °F - Pensky-Martens closed cup

flash_point_c

> 100 °C - Pensky-Martens closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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T1503
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25G
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705578-5MG-PW

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1000309185

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Trifluoroacetic acid HPLC

Supelco

TX1276

Trifluoroacetic acid

Trifluoroacetic acid Meets Reagent Specifications for testing USP/NF monographs

Supelco

TX1275

Trifluoroacetic acid

Enhanced sensitivity for peptide mapping with electrospray liquid chromatography-mass spectrometry in the presence of signal suppression due to trifluoroacetic acid-containing mobile phases
Apffel A, et al.
Journal of Chromatography A, 712(1), 177-190 (1995)
Analysis of trifluoroacetic acid and other short-chain perfluorinated acids (C2--C4) in precipitation by liquid chromatography-tandem mass spectrometry: Comparison to patterns of long-chain perfluorinated acids (C5--C18)
Taniyasu S, et al.
Analytica Chimica Acta, 619(2), 221-230 (2008)
Yukiko Enomoto-Rogers et al.
Carbohydrate polymers, 92(2), 1827-1834 (2013-02-13)
Fully substituted glucomannan triacetate (GMTAc) (degree of substitution (DS)=3.0) was prepared from konjac glucomannan (KGM) treated with acetic acid and trifluoroacetic anhydride (TFAA). The peaks in the (1)H- and (13)C NMR spectra of GMTAc were assigned in detail based on
Caroline Le Maréchal et al.
Veterinary research, 42, 35-35 (2011-02-18)
Staphylococcus aureus is a major cause of mastitis in ruminants. In ewe mastitis, symptoms range from subclinical to gangrenous mastitis. S. aureus factors or host-factors contributing to the different outcomes are not completely elucidated. In this study, experimental mastitis was
Christian D Kelstrup et al.
Journal of proteome research, 13(12), 6187-6195 (2014-10-29)
Shotgun proteomics is a powerful technology for global analysis of proteins and their post-translational modifications. Here, we investigate the faster sequencing speed of the latest Q Exactive HF mass spectrometer, which features an ultra-high-field Orbitrap mass analyzer. Proteome coverage is

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