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76778

Supelco

Methyl acrylate

analytical standard

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Linear Formula:
CH2=CHCOOCH3
CAS Number:
Molecular Weight:
86.09
Beilstein/REAXYS Number:
605396
EC Number:
MDL number:
UNSPSC Code:
85151701
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3 (vs air)

vapor pressure

67.5 mmHg ( 20 °C)

assay

≥99.5% (GC)

autoignition temp.

874 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.0015% hydroquinone monomethyl ether as stabilizer

expl. lim.

14.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.402 (lit.)
n20/D 1.403

bp

80 °C (lit.)

mp

−75 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

SMILES string

COC(=O)C=C

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

InChI key

BAPJBEWLBFYGME-UHFFFAOYSA-N

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General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Application

Methyl acrylate can undergo transesterification reaction with 1-butanol under thermal conditions in the presence of hydrochloric acid to yield butyl acrylate as the major product.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 2

flash_point_f

27.0 °F

flash_point_c

-2.8 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Organic Chemistry (2008)
Jens Voepel et al.
Biomacromolecules, 12(1), 253-259 (2010-12-21)
A multifunctional macroinitiator for single-electron-transfer mediated living radical polymerization (SET-LRP) was designed from acetylated galactoglucomannan (AcGGM) by α-bromoisobutyric acid functionalization of the anomeric hydroxyl groups on the heteropolysaccharide backbone. This macroinitiator, with a degree of substitution of 0.15, was used
Mustafa Ciftci et al.
Chemical communications (Cambridge, England), 48(82), 10252-10254 (2012-09-13)
Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two
Daniel Duncan et al.
Dalton transactions (Cambridge, England : 2003), 40(9), 1998-2005 (2011-01-26)
A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between methyl acrylate and either aryl bromides or iodides, can be recovered intact by fluorous solid-phase extraction
Transformation of nickelalactones to methyl acrylate: on the way to a catalytic conversion of carbon dioxide.
S Y Tina Lee et al.
ChemSusChem, 4(9), 1275-1279 (2011-09-17)

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