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Tetradodecylammonium tetrakis(4-chlorophenyl)borate

Selectophore™

Synonym(s):

ETH 500, Tetrakis(4-chlorophenyl)borate tetradodecylammonium salt

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About This Item

Empirical Formula (Hill Notation):
C72H116BCl4N
CAS Number:
100581-42-8
Molecular Weight:
1148.32
Beilstein/REAXYS Number:
8894894
MDL number:
MFCD00145372
UNSPSC Code:
26111700
PubChem Substance ID:
329769516
NACRES:
NB.61

grade

for ion-selective electrodes

Quality Level

200

product line

Selectophore™

form

powder

mp

79-80 °C

SMILES string

Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4.CCCCCCCCCCCC[N+](CCCCCCCCCCCC)(CCCCCCCCCCCC)CCCCCCCCCCCC

InChI

1S/C48H100N.C24H16BCl4/c1-5-9-13-17-21-25-29-33-37-41-45-49(46-42-38-34-30-26-22-18-14-10-6-2,47-43-39-35-31-27-23-19-15-11-7-3)48-44-40-36-32-28-24-20-16-12-8-4;26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20/h5-48H2,1-4H3;1-16H/q+1;-1

InChI key

OKKRVCFTMNLHTL-UHFFFAOYSA-N

Related Categories

General description

ETH 500 is a lipophilic electrolyte mostly used as an anionic additive.
Visit our Sensor Applications portal to learn more.

Application

ETH 500 has been used in the preparation of:
  • molecularly imprinted polymers, which can be used during potentiometric sensing method for determining neutral phenols.
  • copolymer Ca2+ selective membrane cocktail during electrochemical impedance spectroscopic analysis to study the water intake and layer formation in ion-selective electrode.

Other Notes

Highly lipophilic additive for membranes of neutral carrier-based ion-selective macroelectrodes; Additive in membranes of optodes

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL1851
BCCK0053
BCCH0906
BCCF6640

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Lipophilic and immobilized anionic additives in solvent polymeric membranes of cation-selective chemical sensors.
Rosatzin, Thomas, et al.
Analytica Chimica Acta, 280.2, 197-208 (1993)
D. Ammann et al.
Analytica Chimica Acta, 171, 119-119 (1985)
Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor.
Kou LJ
Analytical and Bioanalytical Chemistry, 405(14), 4931-4936 (2013)
Eduardo Laborda et al.
Angewandte Chemie (International ed. in English), 56(3), 782-785 (2016-12-10)
A new electrochemical framework for tracking individual soft particles in solution and monitoring their fusion with polarized liquid-liquid interfaces is reported. The physicochemical principle lies in the interfacial transfer of an ionic probe confined in the particles dispersed in solution
Elimination of undesirable water layers in solid-contact polymeric ion-selective electrodes.
Veder JP
Analytical Chemistry, 80(17), 6731-6740 (2008)
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