234125
Iron(III) ferrocyanide
Synonym(s):
Ferric ferrocyanide, Ferrihexacyanoferrate, Ferrocin, Prussian blue
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About This Item
Linear Formula:
Fe4[Fe(CN)6]3
CAS Number:
Molecular Weight:
859.23
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-875-5
MDL number:
Form:
powder
InChI key
DNMNDNSFJMUUFM-UHFFFAOYSA-N
InChI
1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
SMILES string
[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N
form
powder
concentration
≥30% (ICP)
λmax
694 nm
Quality Level
Related Categories
Application
Iron(III) ferrocyanidecyclic can be used as:
- A catalyst to synthesize cyclic carbonates by reaction between carbon dioxide and epoxides.
- A precursor to prepare Fe-Fe3C nanoparticle encapsulated N-doped graphene layers via pyrolysis.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Bensu Ertek et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 28(11), 1075-1080 (2012-11-15)
This study investigates a new approach for the electrocatalytic determination of sulfide in a flow injection analysis (FIA) system using a Prussian blue modified glassy carbon electrode (PB/GCE). The results from experiments show that PB/GCE significantly enhances the electrocatalytic activity
Prussian blue as a single precursor for synthesis of Fe/Fe3C encapsulated N-doped graphitic nanostructures as bi-functional catalysts
Barman BK and Nanda KK
Green Chemistry, 18(2), 427-432 (2016)
Guanglei Fu et al.
Talanta, 97, 438-444 (2012-07-31)
A glucose biosensor was fabricated based on electrostatic self-assembly in combination with in situ photo-cross-linking of glucose oxidase (GOx) and diazoresin-chitosan (DAR-CS) on Prussian blue deposited multi-walled carbon nanotubes (PB-MWNTs) backbone. It was demonstrated that GOx was initially ionically deposited
Guanglei Fu et al.
Chemical communications (Cambridge, England), 48(94), 11567-11569 (2012-10-24)
Herein, prussian blue nanoparticles, an ancient dye, were explored as a new generation of near-infrared laser-driven photothermal ablation agents for cancer therapy alternative to traditional agents due to their good photothermal efficiency and high photothermal stability but low cost and
Yanxia Li et al.
Biosensors & bioelectronics, 42, 612-617 (2012-12-25)
In this paper, a novel strategy of protein molecularly-imprinted electrochemical sensor was proposed to determine Bovine Hemoglobin selectively. Gold microdendrites and prussian blue particles were electrodeposited on the surface of glassy carbon electrode respectively to improve the sensitivity of MIECS.
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