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307432

Sigma-Aldrich

1,2-Dimethoxyethane

suitable for HPLC, 99.9%, inhibitor-free

Synonym(s):

mono-Glyme, Dimethylglycol, Ethylene glycol dimethyl ether, Monoglyme

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About This Item

Linear Formula:
CH3OCH2CH2OCH3
CAS Number:
110-71-4
Molecular Weight:
90.12
Beilstein/REAXYS Number:
1209237
EC Number:
203-794-9
MDL number:
MFCD00008502
UNSPSC Code:
12190000
PubChem Substance ID:
329753574
NACRES:
NA.21

vapor density

3.1 (20 °C, vs air)

Quality Level

100

vapor pressure

48 mmHg ( 20 °C)

assay

99.9%

form

liquid

autoignition temp.

396 °F

purified by

glass distillation

expl. lim.

10.4 %

technique(s)

HPLC: suitable

impurities

<0.030% water

refractive index

n20/D 1.379 (lit.)

pH

~7

bp

85 °C (lit.)

mp

−58 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)

λ

H2O reference

UV absorption

λ: 220 nm Amax: 1.00
λ: 250 nm Amax: 0.20
λ: 300 nm Amax: 0.03
λ: 350-400 nm Amax: 0.01

application(s)

food and beverages

SMILES string

COCCOC

InChI

1S/C4H10O2/c1-5-3-4-6-2/h3-4H2,1-2H3

InChI key

XTHFKEDIFFGKHM-UHFFFAOYSA-N

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General description

This solvent is glass distilled, submicron filtered and subjected to rigorous specification testing to provide lot-to-lot consistency.

Application

Designed for use with HPLC instrumentation and organic synthesis applications.

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

41.0 °F - closed cup

flash_point_c

5 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities.
Hugo E. Gottlieb et al.
The Journal of organic chemistry, 62(21), 7512-7515 (2001-10-24)
The catalytic Pauson-Khand reaction promoted by a small amount of 1, 2-dimethoxyethane or water.
Sugihara T and Yamaguchi M.
Synlett, 12, 1384-1386 (1998)
Theoretical study of cation/ether complexes: Alkali metal cations with 1, 2-dimethoxyethane and 12-crown-4.
Hill SE, et al.
The Journal of Physical Chemistry A, 102(21), 3813-3819 (1998)
Taeyun Ku et al.
Nature methods, 17(6), 609-613 (2020-05-20)
We developed entangled link-augmented stretchable tissue-hydrogel (ELAST), a technology that transforms tissues into elastic hydrogels to enhance macromolecular accessibility and mechanical stability simultaneously. ELASTicized tissues are highly stretchable and compressible, which enables reversible shape transformation and faster delivery of probes
Andrew Martins et al.
Organic letters, 12(22), 5186-5188 (2010-10-19)
A palladium-catalyzed crossed biaryl coupling/reduction sequence enables the formation of meta-substituted biaryls via solvent-mediated arylpalladium(II) reduction. Isotope labeling studies determined that the decomposition of 1,2-dimethoxyethane (DME) is indeed involved in the reductive process.
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