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900501

Sigma-Aldrich

Potassium carbonate

anhydrous, free-flowing, Redi-Dri™, ReagentPlus®, 99%

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About This Item

Linear Formula:
K2CO3
CAS Number:
584-08-7
Molecular Weight:
138.21
Beilstein/REAXYS Number:
4267587
EC Number:
209-529-3
MDL number:
MFCD00011382
UNSPSC Code:
12352302
PubChem Substance ID:
24858785
NACRES:
NA.21

grade

anhydrous

Quality Level

100

product line

ReagentPlus®
Redi-Dri™

assay

99%

form

powder

quality

free-flowing

pH

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

SMILES string

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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Application


  • Improved 2-pyridyl reductive homocoupling reaction using biorenewable solvent: A detailed examination of using potassium carbonate in an enhanced reductive homocoupling of 2-pyridyl compounds in a biorenewable solvent, showcasing a sustainable approach to chemical synthesis (Webb et al., 2023).

  • Fe(3)O(4)@void@C-Schiff-base/Pd yolk-shell nanostructures as a nanocatalyst for Suzuki coupling reaction: Discusses the development of a palladium-based nanocatalyst supported by potassium carbonate for improved Suzuki coupling reactions, an important reaction in organic chemistry (Barzkar et al., 2023).

  • Enhanced LC-ESI-MS/MS Sensitivity by Cationic Derivatization of Organophosphorus Acids: Study on enhancing liquid chromatography-electrospray ionization tandem mass spectrometry sensitivity using potassium carbonate, improving the detection of organophosphorus acids (Shamai Yamin et al., 2023).


Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Robert Möckel et al.
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Polyamide interfacial composite membranes prepared from m-phenylene diamine, trimesoyl chloride and a new disulfonated diamine.
Xie W, et al.
Journal of Membrane Science, 403, 152-161 (2012)
Heck reaction using palladium complexed to dendrimers on silica.
Alper H, et al.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)
Carlos Arroniz et al.
Organic letters, 15(4), 910-913 (2013-02-05)
ortho-Arylation of ortho-substituted benzoic acids is a challenging process due to the tendency of the reaction products toward Pd-catalyzed protodecarboxylation. A simple method for preventing decarboxylation in sterically hindered benzoic acids is reported. The method described represents a reliable and
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