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M0753

Sigma-Aldrich

Molybdenum(VI) oxide

ReagentPlus®, ≥99.5%

Synonym(s):

Molybdenum trioxide

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About This Item

Linear Formula:
MoO3
CAS Number:
1313-27-5
Molecular Weight:
143.94
EC Number:
215-204-7
MDL number:
MFCD00003469
UNSPSC Code:
12352303
PubChem Substance ID:
329817827
NACRES:
NA.55

Quality Level

200

product line

ReagentPlus®

assay

≥99.5%

form

crystals

reaction suitability

reagent type: catalyst
core: molybdenum

mp

795 °C (lit.)

cation traces

NH4+: ≤0.02%

SMILES string

O=[Mo](=O)=O

InChI

1S/Mo.3O

InChI key

JKQOBWVOAYFWKG-UHFFFAOYSA-N

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Application

Precursor to LAMOX fast ion conductors and superconductors.
Used in the solid state synthesis of a remarkable ternary, reduced molybdenum oxide, Pr4Mo9O18, whose structure contains previously unknown Mo7, Mo13 and Mo19 clusters. The new cluster product is a small band gap semiconductor.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Yu-Zhan Wang et al.
The Journal of chemical physics, 134(3), 034706-034706 (2011-01-26)
The electronic structures at the MoO(3)∕Co interface were investigated using synchrotron-based ultraviolet and x-ray photoelectron spectroscopy. It was found that interfacial chemical reactions lead to the reduction of Mo oxidation states and the formation of Co-O bonds. These interfacial chemical
Di-Yan Wang et al.
Advanced materials (Deerfield Beach, Fla.), 24(25), 3415-3420 (2012-06-08)
A heterojunction photodiode with NIR photoresponse using solution processable pyrite FeS(2) nanocrystal ink is demonstrated which has the advantages of earth-abundance and non-toxicity. The device consists of a FeS(2) nanocrystal (NC) thin film sandwiched with semiconducting metal oxides with a
Lili Cai et al.
Nano letters, 11(2), 872-877 (2011-01-26)
We report an atmospheric, catalyst-free, rapid flame synthesis technique for growing single, branched, and flower-like α-MoO(3) nanobelt arrays on diverse substrates. The growth rate, morphology, and surface coverage density of the α-MoO(3) nanobelts were controlled by varying the flame equivalence
MoO3 films spin-coated from a nanoparticle suspension for efficient hole-injection in organic electronics.
Jens Meyer et al.
Advanced materials (Deerfield Beach, Fla.), 23(1), 70-73 (2010-10-27)
Kourosh Kalantar-zadeh et al.
Nanoscale, 2(3), 429-433 (2010-07-21)
The formation of MoO(3) sheets of nanoscale thickness is described. They are made from several fundamental sheets of orthorhombic alpha-MoO(3), which can be processed in large quantities via a low cost synthesis route that combines thermal evaporation and mechanical exfoliation.
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