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H9903

Sigma-Aldrich

1-(Heptafluorobutyryl)imidazole

BioReagent, suitable for derivatization

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Synonym(s):
1-(Perfluorobutyryl)imidazole
Empirical Formula (Hill Notation):
C7H3F7N2O
CAS Number:
32477-35-3
Molecular Weight:
264.10
Beilstein:
4488026
EC Number:
251-063-8
MDL number:
MFCD00014503
PubChem Substance ID:
24895875
NACRES:
NA.32

product line

BioReagent

Quality Level

100

bp

158-163 °C (lit.)

suitability

suitable for derivatization

storage temp.

−20°C

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)n1ccnc1

InChI

1S/C7H3F7N2O/c8-5(9,6(10,11)7(12,13)14)4(17)16-2-1-15-3-16/h1-3H

InChI key

MSYHGYDAVLDKCE-UHFFFAOYSA-N

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This Item
74382394912556645
1-(Heptafluorobutyryl)imidazole BioReagent, suitable for derivatization

Sigma-Aldrich

H9903

1-(Heptafluorobutyryl)imidazole

N-Heptafluorobutyrylimidazole for GC derivatization, LiChropur™, ≥98.0% (GC)

Supelco

74382

N-Heptafluorobutyrylimidazole

Heptafluorobutyric anhydride for GC derivatization, LiChropur™, ≥99.0%

Supelco

394912

Heptafluorobutyric anhydride

N-Heptafluorobutyrylimidazole 97%

Sigma-Aldrich

556645

N-Heptafluorobutyrylimidazole

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

product line

BioReagent

product line

-

product line

-

product line

-

suitability

suitable for derivatization

suitability

-

suitability

-

suitability

-

General description

1-(Heptafluorobutyryl)imidazole, also known as HFBI, is an acylating derivatization reagent. It is a mild amine-group derivatizing agent. HFBI doesn’t produce acidic by-products in reaction, and the unutilized reagent doesn’t damage the chromatographic process. Post derivatization reaction, the HFB (Heptafluorobutyryl) derivatives are analyzed chromatographically.

Application

1-(Heptafluorobutyryl)imidazole is used as a derivatizing agent for analysing Sulphur mustard metabolites. It is suitable to study dispersive derivatization of degradation products.

Biochem/physiol Actions

Mild amine-group derivatizing reagent; non-acidic by-product prevents decomposition and reduces GC column degradation.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

170.6 °F - closed cup

Flash Point(C)

77 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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