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Supelco

Bromomethane solution

certified reference material, 200 μg/mL in methanol

Synonym(s):

Methyl bromide

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About This Item

Empirical Formula (Hill Notation):
CH3Br
CAS Number:
74-83-9
Molecular Weight:
94.94
MDL number:
MFCD00000166
UNSPSC Code:
12000000
PubChem Substance ID:
24871979

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

CofA

current certificate can be downloaded

packaging

ampule of 1 mL

concentration

200 μg/mL in methanol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

single component solution

storage temp.

2-8°C

SMILES string

CBr

InChI

1S/CH3Br/c1-2/h1H3

InChI key

GZUXJHMPEANEGY-UHFFFAOYSA-N

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General description

Bromomethane is a broad spectrum fumigant, which can find applications in post-harvest fumigation and pest control of several foods like spices, cereals, nuts, dried fruits, fresh fruits, vegetables, turf and also nursery crops.
Bromomethane is frequently used as fumigant. It is a liquid at room temperature which readily vaporizes into a colourless gas. It is slightly soluble in water and is freely soluble in organic solvents.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Solution of bromomethane may be used in preparation of 2-methoxyisoindoline-1,3- dione.

Other Notes

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
LRAD8388
LRAD4241
LRAD0664
LRAC1992
LRAB8739

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Iodomethane contains copper as stabilizer, ReagentPlus®, 99.5%

Sigma-Aldrich

289566

Iodomethane

Iodomethane purum, ≥99.0% (GC)

Sigma-Aldrich

67692

Iodomethane

EPA 502/524.2 VOC Mix 200 μg/mL each component in methanol, analytical standard

Supelco

47932

EPA 502/524.2 VOC Mix

Handbook of Chemicals and Safety (2016)
The challenge of research and extension to define and implement alternatives to methyl bromide
Noling.W.J and Becker.OJ
Journal of Nematology, 26, 573-573 (1994)
Fortune Ezemobi et al.
Acta crystallographica. Section E, Structure reports online, 70(Pt 12), 456-461 (2015-01-02)
The title compounds, C9H7NO3, (1), C10H7NO5, (2), and C14H9NO5, (3), are three potentially anti-convulsant compounds. Compounds (1) and (2) are isoindoline derivatives and (3) is an iso-quinoline derivative. Compounds (2) and (3) crystallize with two independent mol-ecules (A and B)
Kathryn Hughes Barry et al.
Cancer causes & control : CCC, 23(6), 807-818 (2012-04-25)
Methyl bromide is a genotoxic soil fumigant with high acute toxicity, but unknown human carcinogenicity. Although many countries have reduced methyl bromide use because of its ozone depleting properties, some uses remain in the United States and other countries, warranting
Yulong Xu et al.
The Journal of chemical physics, 137(18), 184501-184501 (2012-11-21)
The bimolecular nucleophilic substitution (S(N)2) reaction of CH(3)Br and OH(-) in aqueous solution was investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology. Reactant complex, transition state, and product complex are identified and characterized in aqueous solution. The potentials
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