Skip to Content
MilliporeSigma

Complex anion inclusion compounds: flexible anion-exchange materials.

Chemical communications (Cambridge, England) (2012-11-24)
Edward R Williams, Rebecca M Leithall, Robert Raja, Mark T Weller
ABSTRACT

Copper chloropyrophosphate frameworks have been synthesised with a wide variety of complex inorganic anions trapped in a large, flexible, one-dimensional pore, with anions including chloride, bromide, phosphate and the complex metal halo-anions PtCl(4)(2-), PdBr(4)(2-), CuCl(4)(2-) and AuCl(4)(-).

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Platinum(IV) chloride, 96%
Sigma-Aldrich
Sodium tetrachloroaurate(III) dihydrate, 99%
Sigma-Aldrich
Gold(III) chloride solution, 99.99% trace metals basis, 30 wt. % in dilute HCl
Sigma-Aldrich
Platinum(IV) chloride, ≥99.9% trace metals basis
Sigma-Aldrich
Platinum(IV) chloride, ≥99.99% trace metals basis
Sigma-Aldrich
Potassium gold(III) chloride, 99.995% trace metals basis
Sigma-Aldrich
Potassium gold(III) chloride, 98%