Electropolymerized Pyrrole-Based Conductive Polymeric Ionic Liquids and Their Application for Solid-Phase Microextraction.

Electropolymerized Pyrrole-Based Conductive Polymeric Ionic Liquids and Their Application for Solid-Phase Microextraction.

ACS applied materials & interfaces (2017-07-05)

Amila M Devasurendra, Cheng Zhang, Joshua A Young, L M Viranga Tillekeratne, Jared L Anderson, Jon R Kirchhoff

ABSTRACT

Pyrrole was covalently bonded to 1-methyl and 1-benzylimidazolium ionic liquids (ILs) via an N-substituted alkyl linkage to prepare electropolymerizable IL monomers with excellent thermal stability. The methylimidazolium IL, [pyrrole-C

MATERIALS

Product Number

Brand

Product Description

291838

Sigma-Aldrich

Propyl butyrate, 99%

D41007

Sigma-Aldrich

1,6-Dibromohexane, 96%

116416

Sigma-Aldrich

1-Benzylimidazole, 99%

215376

Sigma-Aldrich

Acenaphthene, 99%

57311

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57550-U

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SPME StableFlex^™ fiber assortment kit, for use with manual holder

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SPME StableFlex^™ fiber assortment kit, needle size 23 ga, StableFlex fiber, for use with autosampler

57321-U

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SPME fiber assortment kit 2, for use with autosampler, size 24 ga

57551-U

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SPME StableFlex^™ fiber assortment kit, needle size 24 ga, for use with autosampler

57286-U

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SPME fiber assortment kit 2, for use with autosampler, needle size 23 ga

57902-U

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SPME Fiber Assembly Polydimethylsiloxane/Divinylbenzene (PDMS/DVB), d_f 65 μm(PDMS/DVB, for use with autosampler, needle size 23 ga, metal alloy fiber

57362-U

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SPME fiber assortment kit 5, needle size 23 ga, for use with autosampler

57324-U

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SPME fiber assortment kit 4, for use with manual holder, size 24 ga

57287-U

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SPME fiber assortment kit 4, for use with autosampler, needle size 23 ga

57307

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57325-U

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SPME fiber assortment kit 4, for use with autosampler, size 24 ga

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SPME fiber assortment kit 1, for use with autosampler, needle size 23 ga

57306

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SPME fiber assortment kit 1, for use with manual holder, needle size 24 ga

57320-U

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SPME fiber assortment kit 2, for use with manual holder, needle size 24 ga

571245

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Pyrene, sublimed grade, 99%

452912

Sigma-Aldrich

Sodium hydride, 60 % dispersion in mineral oil

57341-U

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SPME Fiber Assembly Polydimethylsiloxane/Divinylbenzene (PDMS/DVB), d_f 65 μm(PDMS/DVB, needle size 24 ga, for use with manual holder