Heterogeneous Catalysts for Synthetic Applications

The use of heterogeneous catalysts for synthetic applications such as hydrogenation, oxidation, or coupling reactions allows for faster, large-scale productions and selective product formation. The Evonik solid heterogeneous catalysts portfolio has been created with a variety of metals: Pd, Pt, Ru, and Rh with the metal present on the active carbon for most. Controlling the percent metal and the structure of the carbon changes the reactivity broadening the application possibilities.

The tables below summarize the applications of these diverse catalysts categorized by reaction type. For a complete application guide, please see the download link below.

 

⚫ Preferred (first choice)
⚪ Recommended 

HYDROGENATION OF C-C BONDS

	CC Double Bonds & CC Triple Bonds	CC Triple Bonds to CC Double Bonds	Fatty Acid and Fat Hardening
5% Pd on activated carbon (907944)	⚫		⚪
5% Pd on activated carbon (908061)	⚫
5% Pd on activated carbon (907987)	⚫
5% Pd on activated carbon (907995)	⚪		⚪
5% Pd on activated carbon (908096)	⚪		⚫
10% Pd on activated carbon (908029)	⚪		⚪
5% Pd on activated carbon (908118)	⚪
5% Pd on calcium carbonate (908002)		⚫
5% Pd on calcium carbonate (908134)		⚫
5% Pt on activated carbon (908037)	⚫

HYDROGENATION OF C-N BONDS

	CN Triple Bonds to Primary Amines & Aldehydes	CN Triple Bonds to 2°/3° Amines	CN Double Bonds (Imines)	Hydrazones to Hydrazides
5% Pd on activated carbon (907944)	⚫
5% Pd on activated carbon (908061)	⚫
5% Pd on activated carbon (908096)	⚪
10% Pd on activated carbon (908029)	⚪
5% Pd on activated carbon (908118)	⚪
3% Pt on activated carbon (908169)		⚪	⚪	⚪
5% Pt on activated carbon (908053)		⚫	⚪	⚫
5% Pt on activated carbon (908150)		⚪	⚫	⚪
5% Pt on activated carbon (908037)		⚫	⚫	⚫
5% Rh on activated carbon (680710)	⚪*

*only for primary amines

HYDROGENATION OF C=O BONDS

	Aliphatic Aldehydes and Ketones	Sugars to Sugar Alcohols	Aromatic Carbonyls to Alcohols	Aromatic Carbonyls to Alkyls
5% Pd on activated carbon (907138)			⚫
10% Pd on activated carbon (330108)				⚫
20% Pd on activated carbon (330094)				⚪
5% Pd on activated carbon (907839)				⚫
5% Pd on activated carbon (907944)			⚪	⚫
5% Pd on activated carbon (908061)			⚪
5% Pd on activated carbon (907987)			⚫
5% Pd on activated carbon (908096)				⚪
10% Pd on activated carbon (908029)				⚪
5% Pt on activated carbon (908053)			⚫
5% Pt on activated carbon (908150)	⚪		⚪
5% Pt on activated carbon (908037)	⚫		⚫
3% Pt on activated carbon (908088)
10% Pt on activated carbon (907812)	⚪		⚪
5% Ru on activated carbon (908045)	⚫	⚫		⚫
5% Ru on activated carbon (907871)	⚫	⚫		⚪
5% Ru on alumina (908142)	⚪	⚪		⚫

HYDROGENATION OF NITRO GROUPS

	Aromatic Nitro Groups to Aromatic Amines	Aromatic Nitro Groups to Halonitroamromatics	Aromatic Nitro Groups to Hydroxylamines	Aliphatic Nitro Groups
5% Pd on activated carbon (907138)				⚪
5% Pd on activated carbon (908061)	⚫			⚫
5% Pd on activated carbon (907987)				⚪
5% Pd on activated carbon (908096)	⚫
5% Pd on activated carbon (908118)				⚫
5% Pd on calcium carbonate (908002)			⚫
5% Pd on alumina (908126)			⚫
4% Pd + 1% Pt on activated carbon (907936)	⚪
3% Pt on activated carbon (908169)	⚫	⚪
5% Pt on activated carbon (908053)	⚫	⚪		⚪
5% Pt on activated carbon (908150)	⚪	⚪		⚫
5% Pt on activated carbon (908037)		⚪		⚪
3% Pt on activated carbon (908088)	⚪	⚪	⚫
10% Pt on activated carbon (907812)		⚪
2% Pt on activated carbon (907952)	⚪	⚫
1% Pt on activated carbon (907820)		⚫
1% Pt on activated carbon (907898)	⚪	⚫

HYDROGENATION OF AROMATICS

	Heteroaromatics	Aromatics (partial)	Aromatics (total)
5% Pd on activated carbon (907138)	⚫
5% Pd on activated carbon (907944)	⚫
5% Pd on activated carbon (908096)	⚪
10% Pd on activated carbon (908029)	⚪
5% Pd on activated carbon (908118)	⚪
5% Rh on activated carbon (680710)	⚫		⚫
5% Ru on activated carbon (908045)	⚪	⚫	⚪
5% Ru on activated carbon (907871)	⚪	⚫	⚪
5% Ru on alumina (908142)	⚪	⚫	⚪

HYDROGENOLYSIS REACTIONS

	O/N-Debenzylation	Removal of Cbz (Z)	Rosenmund Reduction
5% Pd on activated carbon (907138)		⚫
10% Pd on activated carbon (330108)	⚫	⚫
20% Pd on activated carbon (330094)	⚫	⚪
5% Pd on activated carbon (907839)	⚫
5% Pd on activated carbon (907944)	⚪
5% Pd on activated carbon (908061)	⚪
5% Pd on activated carbon (907987)		⚫	⚫
5% Pd on activated carbon (908096)	⚪
10% Pd on activated carbon (908029)	⚪	⚪
5% Pd on activated carbon (908118)		⚫	⚫
4% Pd + 1% Pd on activated carbon (907936)	⚪	⚪

Hydrodehalogenation Reactions

	Hydrodehalogenation of Aliphatics	Hydrodehalogenation of Aromatics
5% Pd on activated carbon (907138)	⚫	⚫
5% Pd on activated carbon (907944)		⚪
5% Pd on activated carbon (908061)	⚪	⚪
5% Pd on activated carbon (907987)	⚫	⚫
10% Pd on activated carbon (908029)		⚪
5% Pd on activated carbon (908118)	⚫	⚫

REDUCTIVE ALKYLATION AND AMINATION

	Aldehydes and Ketones to Primary Amines	Aldehydes and Ketones to Secondary Amines
5% Pd on activated carbon (907138)	⚪	⚪
5% Pd on activated carbon (907944)	⚫	⚫
5% Pd on activated carbon (907995)	⚪	⚪
5% Pd on activated carbon (908096)	⚪	⚪
5% Pd on activated carbon (908118)	⚫	⚫
3% Pt on activated carbon (908169)		⚪
5% Pt on activated carbon (908053)		⚪
3% Pt on activated carbon (908088)		⚫

DEHYDROGENATIONS AND OXIDATIONS

	Dehydrogenation of Carbocyclic Rings to Aromatics	Oxidations of Alcohols to Sugars
5% Pd on activated carbon (907138)	⚫
5% Pd on activated carbon (908061)	⚪
5% Pd on activated carbon (907987)	⚫
10% Pd on activated carbon (908029)		⚪
5% Pd on activated carbon (908118)	⚫
3% Pt on activated carbon (908169)		⚪
5% Pt on activated carbon (908053)		⚪
5% Pt on activated carbon (908150)		⚪
5% Pt on activated carbon (908037)		⚪
10% Pt on activated carbon (907812)		⚪
5% Pt on activated carbon (908010)		⚫

C-C COUPLING REACTIONS

	Heck Reaction	Suzuki Coupling
5% Pd on activated carbon (907138)	⚫	⚫
10% Pd on activated carbon (330108)	⚪	⚪
5% Pd on activated carbon (907944)	⚫	⚫
5% Pd on activated carbon (908061)	⚫	⚫
5% Pd on activated carbon (907987)	⚫	⚫