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品質水準
アッセイ
98%
形状
solid
mp
48-50 °C (lit.)
官能基
ester
SMILES記法
CC1=CC(C)=CC(=O)O1
InChI
1S/C7H8O2/c1-5-3-6(2)9-7(8)4-5/h3-4H,1-2H3
InChI Key
IXYLIUKQQQXXON-UHFFFAOYSA-N
遺伝子情報
human ... CYP1A2(1544)
詳細
4,6-Dimethyl-α-pyrone was immobilized in a guanidinium-sulfonate-calixarene (G4C) crystalline network, which upon exposure to ultraviolet irradiation, transforms the entrapped 4,6-dimethyl-α-pyrone into a 4,6-dimethyl-β-lactone. Thin solid films layers of 4,6-dimethyl-α-pyrone on UV irradiation at -190°C were investigated.
アプリケーション
4,6-Dimethyl-α-pyrone (Me21) has been used in the preparation of G4C{Me21} via reacting with tetra-p-sulfocalix[4]arene (C) and guanidine hydrochloride (GCl). It may be used in the preparation of host-guest complex G4C{Me21} by reacting with crystalline guanidinium-sulfonate-calixarene (G4C). This complex on UV irradiation afforded 1,3-dimethylcyclobutadiene (Me2CBD).
保管分類コード
11 - Combustible Solids
WGK
WGK 3
引火点(°F)
Not applicable
引火点(℃)
Not applicable
個人用保護具 (PPE)
Eyeshields, Gloves, type N95 (US)
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Jan Code
370207-VAR:
370207-5G:
370207-25G:
370207-BULK:
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Single-crystal X-ray structure of 1,3-dimethylcyclobutadiene by confinement in a crystalline matrix.
Yves-Marie Legrand et al.
Science (New York, N.Y.), 329(5989), 299-302 (2010-07-22)
Cyclobutadiene (CBD), the smallest cyclic hydrocarbon bearing conjugated double bonds, has long intrigued chemists on account of its strained geometry and electronic instability, but the parent compound and its unperturbed derivatives have thus far eluded crystallographic characterization. In this work
4, 6-Dimethyl-a-pyrone: a matrix isolation study of the photochemical generation of conjugated ketene, Dewar valence isomer and 1, 3-dimethyl-cyclobutadiene.
Breda S, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 162(1), 139-151 (2004)
Yves-Marie Legrand et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(36), 10021-10028 (2011-09-08)
Cyclobutadiene (CBD), the smallest cyclic hydrocarbon bearing conjugated double bonds, has long intrigued chemists because of its chemical characteristics. The question of whether the molecule could be prepared at all has been answered, but the parent compound and its unperturbed
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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