563722

3-クロロフェニルマグネシウムブロミド

0.5 M in THF

• 別名: (3-Chlorophenyl)magnesium bromide, (m-Chlorophenyl)magnesium bromide, 3-chloro phenyl magnesium bromide, 3-chlorophenyl magnesium bromide, m-chlorophenyl magnesium bromide, Bromo(3-chlorophenyl)magnesium
• 実験式（ヒル表記法）: C₆H₄BrClMg
• CAS番号: 36229-42-2
• 分子量: 215.76
• MDL番号: MFCD00672003
• UNSPSCコード: 12352103
• PubChem Substance ID: 24880124
• NACRES: NA.22

特性

• 反応適合性: reaction type: Grignard Reaction
• 品質水準: 100
• 濃度: 0.5 M in THF
• bp: 65 °C (lit.)
• 密度: 0.960 g/mL at 25 °C (lit.)
• 官能基: chloro
• 保管温度: 2-8°C
• SMILES記法: Clc1cccc([Mg]Br)c1
• InChI: 1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1
• InChI Key: ZIYRUWPTUPFRQU-UHFFFAOYSA-M

詳細

アプリケーション

3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:

• 2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
• 2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
• 2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.

法的情報

Rieke^® Metals, Inc.の製品です。

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H302,H319,H335,H351
• 注意書き: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): <1.4 °F - closed cup
• 引火点(℃): < -17 °C - closed cup