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Merck
모든 사진(3)

Key Documents

135623

Sigma-Aldrich

Dimethyl oxalate

ReagentPlus®, 99%

동의어(들):

Methyl oxalate

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About This Item

Linear Formula:
CH3OCOCOOCH3
CAS Number:
Molecular Weight:
118.09
Beilstein:
1071744
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

제품 라인

ReagentPlus®

분석

99%

형태

powder

refractive index

n20/D 1.39 (lit.)

bp

163.5 °C (lit.)

mp

50-54 °C (lit.)

solubility

ethanol: soluble 50 mg/mL, clear to very slightly hazy, colorless

density

1.148 g/mL at 25 °C (lit.)

SMILES string

COC(=O)C(=O)OC

InChI

1S/C4H6O4/c1-7-3(5)4(6)8-2/h1-2H3

InChI key

LOMVENUNSWAXEN-UHFFFAOYSA-N

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일반 설명

Dimethyl oxalate undergoes Cu/SiO2 catalyzed hydrogenation to yield ethylene glycol. It undergoes selective gas-phase hydrogenation catalyzed by Ag/SiO2 to yield corresponding alcohol.

애플리케이션

Dimethyl oxalate (DMO) was used as alternate fuel in direct oxidation fuel cell. DMO was used to study the IR spectra of DMO isolated in noble gas low-temperature matrices.

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

167.0 °F - closed cup

Flash Point (°C)

75 °C - closed cup

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

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문서 라이브러리 방문

이미 열람한 고객

A1h NMR Pulse Gradient Spin-Echo (PGSE) Mass Transport Study of Dimethyl Oxalate and Ethylene Glycol: New Fuels for the DOFC.
Suarez-Gustave S, et al.
Electrochemical and Solid-State Letters, 12(3), 525-528 (2000)
Molecular structure and infrared spectra of dimethyl oxalate.
Lopes SB, et al.
Physical Chemistry Chemical Physics, 4(6), 1014-1020 (2002)
Chao Wen et al.
Chemical communications (Cambridge, England), 49(45), 5195-5197 (2013-05-02)
The variation of the supports on the Cu/SiO2 catalyst plays an important role in the catalytic performance for hydrogenation of dimethyl oxalate. The loss of silica in the form of tetramethoxysilane from the support under the reaction conditions is responsible
Anyuan Yin et al.
Chemical communications (Cambridge, England), 46(24), 4348-4350 (2010-05-14)
Ag/SiO(2) prepared by a sol-gel process is highly effective for selective gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. The catalysts are of great potential as industrially viable and novel catalysts for the production of methyl glycolate and ethylene glycol.

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