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Merck
모든 사진(6)

문서

517127

Sigma-Aldrich

Dimethyl carbonate

greener alternative

anhydrous, ≥99%

동의어(들):

DMC, Carbonic acid dimethyl ester

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About This Item

Linear Formula:
(CH3O)2CO
CAS Number:
Molecular Weight:
90.08
Beilstein:
635821
EC Number:
MDL number:
UNSPSC 코드:
12352108
PubChem Substance ID:
NACRES:
NA.21

Grade

anhydrous

Quality Level

vapor density

3.1 (vs air)

vapor pressure

18 mmHg ( 21.1 °C)

분석

≥99%

형태

liquid

expl. lim.

4.22-12.87 % (lit.)

환경친화적 대안 제품 특성

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

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불순물

<0.002% water
<0.005% water (100mL pkg)

색상

APHA: <50

refractive index

n20/D 1.368 (lit.)

bp

90 °C (lit.)

mp

2-4 °C (lit.)

density

1.069 g/mL at 25 °C (lit.)

환경친화적 대안 카테고리

SMILES string

O=C(OC)OC

InChI

1S/C3H6O3/c1-5-3(4)6-2/h1-2H3

InChI key

IEJIGPNLZYLLBP-UHFFFAOYSA-N

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일반 설명

Dimethyl carbonate (DMC) is a versatile, non-toxic, biodegradable reagent with tunable chemical reactivity. It serves as a green alternative to dimethyl sulfate or methyl halides and phosgene for methylation and carboxylation reactions. DMC can be prepared by the base-catalyzed reaction between carbon dioxide and methanol.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a Greener alternative to conventional solvents and chemicals. Click here for more information.

애플리케이션

Dimethyl carbonate has been used to dissolve poly (lactic-co-glycolic acid) (PLGA) to form PLGA-coated bioactive glass-ceramic scaffolds.

특징 및 장점

Greener solvent

픽토그램

Flame

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

60.8 °F - closed cup

Flash Point (°C)

16 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Hao Sun et al.
Nature communications, 10(1), 3302-3302 (2019-07-26)
Rechargeable sodium metal batteries with high energy density could be important to a wide range of energy applications in modern society. The pursuit of higher energy density should ideally come with high safety, a goal difficult for electrolytes based on
Direct synthesis of dimethyl carbonate from carbon dioxide and methanol catalyzed by base.
Fang S and Fujimoto K.
Applied Catalysis A: General, 142(1), L1-L3 (1996)
Preparation and characterisation of plga-coated porous bioactive glass-ceramic scaffolds for subchondral bone tissue engineering.
O'Shea TM and Miao X.
Proceeding of the 9th International Symposium on Ceramic Materials and Components for Energy and Environmental Applications (2009)
Zul Ilham et al.
Bioresource technology, 101(8), 2735-2740 (2009-11-26)
This study reports on a novel two-step process for biodiesel production consisting of hydrolysis of oils in sub-critical water and subsequent supercritical dimethyl carbonate esterification. This process found to occur optimally at the sub-critical water treatment (270 degrees Celsius/27 MPa)
Liping Zhang et al.
Bioresource technology, 101(21), 8144-8150 (2010-07-02)
The transesterification of palm oil with dimethyl carbonate (DMC) for preparing biodiesel has been studied in solvent-free system at the catalysis of potassium hydroxide (KOH) as heterogeneous catalyst. Fatty acid methyl esters (FAMEs) were analyzed by GC with internal standard

문서

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

관련 콘텐츠

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