D152927

Dimethyl carbonate

ReagentPlus^®, 99%

• 동의어(들): Carbonic acid dimethyl ester
• Linear Formula: (CH₃O)₂CO
• CAS Number: 616-38-6
• Molecular Weight: 90.08
• Beilstein: 635821
• EC Number: 210-478-4
• MDL number: MFCD00008420
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57654072
• NACRES: NA.21
• 분석: 99%
• bp: 90 °C (lit.)
• vapor pressure: 18 mmHg ( 21.1 °C)

속성

• vapor density: 3.1 (vs air)
• Quality Level: 200
• vapor pressure: 18 mmHg ( 21.1 °C)
• 제품 라인: ReagentPlus^®
• 분석: 99%
• 양식: liquid
• 환경친화적 대안 제품 특성: Less Hazardous Chemical Syntheses; Safer Solvents and Auxiliaries; Design for Degradation; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• refractive index: n20/D 1.368 (lit.)
• bp: 90 °C (lit.)
• mp: 2-4 °C (lit.)
• density: 1.069 g/mL at 25 °C (lit.)
• 환경친화적 대안 카테고리: , Aligned
• SMILES string: O=C(OC)OC
• InChI: 1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
• InChI key: IEJIGPNLZYLLBP-UHFFFAOYSA-N

설명

일반 설명

Dimethyl carbonate (DMC) is a versatile, non-toxic, biodegradable reagent with tunable chemical reactivity. It serves as a green alternative to dimethyl sulfate or methyl halides and phosgene for methylation and carboxylation reactions. The base-catalyzed reaction between carbon dioxide and methanol to form DMC has been studied. Various thermodynamic parameters of DMC have been reported.

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애플리케이션

Dimethyl carbonate may be used to synthesize:

• Methyl phenyl carbonate by transesterification with phenol.
• Diphenyl carbonate by transesterification with methyl phenyl carbonate.
• Methyl carbamates, a raw material for isocyanate synthesis.
• Tetramethoxysilane by reacting with silica at 550-600K.

특징 및 장점

Greener solvent

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS02
• 신호어: Danger
• 유해 및 위험 성명서: H225
• 예방조치 성명서: P210 - P233 - P240 - P241 - P242 - P243
• Hazard Classifications: Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point (°F): 60.8 °F - closed cup
• Flash Point (°C): 16 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter