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Merck
모든 사진(1)

문서

167150

Sigma-Aldrich

1-Bromo-4-nitrobenzene

99%

동의어(들):

1-Bromo-4-nitrobenzene, 1-Nitro-4-bromobenzene, 4-Bromo-1-nitrobenzene, 4-Nitro-1-bromobenzene, 4-Nitrobromobenzene, 4-Nitrophenyl bromide, p-Bromonitrobenzene, p-Nitrophenyl bromide

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About This Item

Linear Formula:
BrC6H4NO2
CAS Number:
Molecular Weight:
202.01
Beilstein:
636964
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

99%

형태

solid

bp

255-256 °C (lit.)

mp

124-126 °C (lit.)

SMILES string

[O-][N+](=O)c1ccc(Br)cc1

InChI

1S/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H

InChI key

ZDFBKZUDCQQKAC-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Electrochemical reduction of 1-bromo-4-nitrobenzene at zinc microelectrodes in ionic liquid has been investigated by cyclic voltammetry. 1-Bromo-4-nitrobenzene undergoes palladium-catalyzed Stille cross coupling reaction with furan-2-yltributyltin using Dabco(triethylenediamine) as ligand. It reacts with p-cresol to yield 1-methyl-4-(4-nitrophenoxy)benzene.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

예방조치 성명서

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

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문서 라이브러리 방문

Jin-Heng Li et al.
The Journal of organic chemistry, 70(7), 2832-2834 (2005-03-25)
[reaction: see text] An efficient Pd(OAc)2/Dabco-catalyzed Stille cross-coupling reaction procedure has been developed. In the presence of Pd(OAc)2 and Dabco (triethylenediamine), various aryl halides including aryl iodides, aryl bromides, and activated aryl chlorides were coupled efficiently with organotin compounds to
Evgeniy G Gordeev et al.
PloS one, 13(6), e0198370-e0198370 (2018-06-08)
Additive manufacturing with fused deposition modeling (FDM) is currently optimized for a wide range of research and commercial applications. The major disadvantage of FDM-created products is their low quality and structural defects (porosity), which impose an obstacle to utilizing them
Sven Ernst et al.
Physical chemistry chemical physics : PCCP, 16(10), 4478-4482 (2014-01-30)
The electrochemical reduction of 1-bromo-4-nitrobenzene (p-BrC6H4NO2) at zinc microelectrodes in the [C4mPyrr][NTf2] ionic liquid was investigated via cyclic voltammetry. The reduction was found to occur via an EC type mechanism, where p-BrC6H4NO2 is first reduced by one electron, quasi-reversibly, to
Synthesis of diaryl ethers using an easy-to-prepare, air-stable, soluble copper (I) catalyst.
Gujadhur R and Venkataraman D.
Synthetic Communications, 31(18), 2865-2879 (2001)
Xiao Yan et al.
Physical chemistry chemical physics : PCCP, 22(11), 6222-6230 (2020-03-05)
Unveiling the reaction mechanism is significant for developing high-performance catalysts. In this paper, a series of precisely controlled PdxM147-x (M = Cu, Pt, Au, Rh, Ru) dendrimer encapsulated nanoparticles (DENs) has been successfully synthesized. The mechanisms of PdxM147-x as catalysts

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