추천 제품
분석
≥97%
mp
90-94 °C (lit.)
solubility
acetone: soluble 74.4 g/100ml at 20 °C(lit.)
benzene: soluble 44.4 g /100ml at 20 °C(lit.)
dioxane: soluble 65.6 g/100ml at 20 °C(lit.)
hexane: soluble 0.4 g/100ml at 20 °C(lit.)
isopropanol: soluble 21 g/100ml at 20 °C(lit.)
작용기
chloro
sulfone
SMILES string
Clc1ccc(cc1)S(=O)(=O)c2ccccc2
InChI
1S/C12H9ClO2S/c13-10-6-8-12(9-7-10)16(14,15)11-4-2-1-3-5-11/h1-9H
InChI key
OFCFYWOKHPOXKF-UHFFFAOYSA-N
일반 설명
4-Chlorophenyl phenyl sulfone is also referred to as sulphenone. It participates in palladium-catalyzed amidation reaction in the presence of low CO pressures and an iodide salt.
애플리케이션
4-Chlorophenyl phenyl sulfone was employed in polyetherification reaction of 4,4′-dihalodiphenyl sulfones.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
Reductive dehalogenation versus substitution in the polyetherification of 4, 4'-dihalodiphenyl sulfones with bisphenolates.
Percec V, et al.
Macromolecules, 26(14), 3650-3662 (1993)
Robert J. Perry et al.
The Journal of organic chemistry, 61(21), 7482-7485 (1996-10-18)
The palladium-catalyzed amidation of electron-deficient aryl chlorides proceeds readily in the presence of low CO pressures and a slight excess of an iodide salt. The rates of amidation are accelerated over those without added salt, and iodide is preferred over
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