모든 사진(1)
About This Item
Linear Formula:
CNCH2COOCH3
CAS Number:
Molecular Weight:
99.09
Beilstein:
3537963
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![1,8-Diazabicyclo[5.4.0]undec-7-ene 98%](/deepweb/assets/sigmaaldrich/product/structures/120/564/5b373e23-1624-489c-8efb-692de0f96ffb/640/5b373e23-1624-489c-8efb-692de0f96ffb.png)
Grade
technical grade
Quality Level
분석
95%
양식
liquid
refractive index
n20/D 1.417 (lit.)
bp
75-76 °C/10 mmHg (lit.)
density
1.09 g/mL at 25 °C (lit.)
작용기
amine
ester
isonitrile
저장 온도
2-8°C
SMILES string
COC(=O)C[N+]#[C-]
InChI
1S/C4H5NO2/c1-5-3-4(6)7-2/h3H2,2H3
InChI key
CRXFROMHHBMNAB-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
일반 설명
Methyl isocyanoacetate undergoes direct aldol reaction with carbonyl compounds in the presence of solid-phase catechol-copper network catalyst to yield corresponding oxazolines. It also participates in four-component Ugi condensation reaction.
애플리케이션
Methyl isocyanoacetate has been used in the copper-catalyzed, diastereoselective synthesis of oxazolines.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
183.2 °F - closed cup
Flash Point (°C)
84 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Hidetoshi Ohta et al.
Chemistry, an Asian journal, 6(9), 2545-2549 (2011-07-14)
The development of a highly active solid-phase catechol-copper network catalyst for direct aldol reaction is described. The catalyst was prepared from an alkyl-chain-linked bis(catechol) and a copper(II) complex. The direct aldol reaction between carbonyl compounds (aldehydes and ketones) and methyl
Tetrahedron Letters, 47, 8641-8641 (2006)
X C Liu et al.
Biotechnology and bioengineering, 69(4), 457-460 (2000-06-22)
The chemoenzymatic preparation of a nine-member Ugi condensation library is described. The carboxylic acid and amine precursors are based on 3-hydroxybutyrate and 4-amino-1-butanol, respectively, and have been acylated selectively using a variety of acyl donors catalyzed by porcine pancreatic lipase.
Stefan Oelmann et al.
Biomacromolecules, 20(1), 90-101 (2018-06-06)
A Passerini three-component polymerization was performed for the synthesis of amphiphilic star-shaped block copolymers with hydrophobic cores and hydrophilic coronae. The degree of polymerization of the hydrophobic core was varied from 5 to 10 repeating units, and the side chain
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