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Merck
모든 사진(1)

주요 문서

245275

Sigma-Aldrich

Triethylphosphine

99%

동의어(들):

Triethylphosphorus

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About This Item

Linear Formula:
(C2H5)3P
CAS Number:
Molecular Weight:
118.16
Beilstein:
969170
EC Number:
MDL number:
UNSPSC 코드:
12352128
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99%

형태

liquid

반응 적합성

reagent type: ligand
reaction type: Arylations

refractive index

n20/D 1.456 (lit.)

bp

127-128 °C (lit.)

density

0.802 g/mL at 20 °C (lit.)

작용기

phosphine

SMILES string

CCP(CC)CC

InChI

1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

RXJKFRMDXUJTEX-UHFFFAOYSA-N

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관련 카테고리

애플리케이션

Triethylphosphine is generally used as a ligand in the organometallic chemistry. It can be used in:
  • Synthesis of the tetrahedrally coordinated L3Fe-Nx complex with a terminal nitride group.
  • Synthesis of (PEt3)2Ni(η2-C14H10), a source of the reactive Ni(PEt3)2 moiety.
  • Synthesis of dinuclear rhodium complexes with triethyllphosphane bridges.

기타 정보

This container should be opened only by a technically qualified person.

픽토그램

FlameCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Unexpected Intermediates and Products in the C? F Bond Activation of Tetrafluorobenzenes with a Bis (triethylphosphine) Nickel Synthon: Direct Evidence of a Rapid and Reversible C? H Bond Activation by Ni (0).
Johnson S A, et al.
Journal of the American Chemical Society, 130(51), 17278-17280 (2008)
Breaking the Rule: Synthesis and Molecular Structure of Dinuclear Rhodium Complexes with Bridging and Semibridging Trialkylphosphane Ligands.
Pechmann T, et al.
Angewandte Chemie (International Edition in English), 39(21), 3909-3911 (2000)
A Tetrahedrally Coordinated L3Fe? N x Platform that Accommodates Terminal Nitride (FeIV? N) and Dinitrogen (FeI? N2? FeI) Ligands.
Betley T A and Peters J C
Journal of the American Chemical Society, 126(20), 6252-6254 (2004)
Matthew R Richardson et al.
Proteomics, 9(9), 2468-2483 (2009-04-30)
Although low-density lipoprotein (LDL) plays a predominant role in atherogenesis, the low-density lipoproteome has not been fully characterized. Moreover, alterations from a Western diet, diabetes, and physical inactivity on this proteome have yet to be determined. Accordingly, relative quantification was
Sarah A Weicker et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(37), 13027-13034 (2015-08-01)
Silyl triflates of the form R4-n Si(OTf)n (n=1, 2; OTf=OSO3 CF3 ) are shown to activate carbon dioxide when paired with bulky alkyl-substituted Group 15 bases. Combinations of silyl triflates and 2,2,6,6-tetramethylpiperidine react with CO2 to afford silyl carbamates via a

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