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일반 설명
Urea hydrogen peroxide (UHP) is an oxidizing agent consisting of urea and hydrogen peroxide. In the presence of carboxylic anhydrides, UHP is employed in a variety of oxidative conversions in anhydrous organic solvents. UHP is used as a hydrogen peroxide source in the oxidation reaction.
애플리케이션
Urea hydrogen peroxide can be used as an oxidizing agent:
- In the conversion of sulfides to sulfoxides or sulfones under solvent free condition.
- In the conversion of nitrogen heterocycles to their corresponding N-oxides.
- In the epoxidation of various alkene in combination with number of carboxylic anhydrides and disodium hydrogen phosphate in anhydrous organic solvents.
- In the Baeyer–Villiger oxidation reaction where in aldehydes and ketones undergo oxidation to produce esters and lactones using various peroxycarboxylic acids.
특징 및 장점
UHP is:
- Inexpensive.
- Stable.
- Easy handling reagent.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Ox. Sol. 3 - Skin Irrit. 2
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
The Urea?Hydrogen Peroxide Complex:? Solid-State Oxidative Protocols for Hydroxylated Aldehydes and Ketones (Dakin Reaction), Nitriles, Sulfides, and Nitrogen Heterocycles
Organic Letters, 1(2), 189?192-189?192 (1999)
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