모든 사진(1)
About This Item
Linear Formula:
CCl3C(=NH)OC(CH3)3
CAS Number:
Molecular Weight:
218.51
Beilstein:
1770049
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![1,8-Diazabicyclo[5.4.0]undec-7-ene 98%](/deepweb/assets/sigmaaldrich/product/structures/120/564/5b373e23-1624-489c-8efb-692de0f96ffb/640/5b373e23-1624-489c-8efb-692de0f96ffb.png)
Quality Level
분석
96%
refractive index
n20/D 1.456 (lit.)
bp
65 °C/11 mmHg (lit.)
mp
21 °C (lit.)
density
1.221 g/mL at 25 °C (lit.)
작용기
chloro
ether
저장 온도
2-8°C
SMILES string
CC(C)(C)OC(=N)C(Cl)(Cl)Cl
InChI
1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3
InChI key
CQXDYHPBXDZWBA-UHFFFAOYSA-N
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관련 카테고리
애플리케이션
tert-Butyl 2,2,2-trichloroacetimidate may be used in the synthesis of N-α-Fmoc-phospho(1-nitrophenylethyl-2-cyanoethyl)-L-serine, caged building block. It may be used in the conversion of alcohols and carboxylic acids to their respective ethers and esters.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
131.0 °F - closed cup
Flash Point (°C)
55 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
Journal of the Chemical Society. Perkin Transactions 1, 2247-2247 (1985)
Deborah M Rothman et al.
The Journal of organic chemistry, 68(17), 6795-6798 (2003-08-16)
Three 1-(2-nitrophenyl)ethyl-caged phospho-amino acids have been synthesized for use in standard N(alpha)-fluorenylmethoxycarbonyl-based solid-phase peptide synthesis (SPPS). The most common naturally occurring phospho-amino acids, serine, threonine, and tyrosine, were prepared as protected caged building blocks by modification with a unique phosphitylating
Tetrahedron Letters, 29, 2483-2483 (1988)
Maiyun Yang et al.
Nature communications, 5, 4981-4981 (2014-09-23)
Bioorthogonal reactions, especially the Cu(I)-catalysed azide-alkyne cycloaddition, have revolutionized our ability to label and manipulate biomolecules under living conditions. The cytotoxicity of Cu(I) ions, however, has hindered the application of this reaction in the internal space of living cells. By
Brett J Roberts et al.
Journal of cell science, 127(Pt 17), 3782-3793 (2014-07-09)
Desmosomes are prominent adhesive junctions found in various epithelial tissues. The cytoplasmic domains of desmosomal cadherins interact with a host of desmosomal plaque proteins, including plakophilins, plakoglobin and desmoplakin, which, in turn, recruit the intermediate filament cytoskeleton to sites of
문서
Trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.
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