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Merck
모든 사진(1)

문서

364789

Sigma-Aldrich

tert-Butyl 2,2,2-trichloroacetimidate

96%

동의어(들):

TBTA

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모든 사진(1)

About This Item

Linear Formula:
CCl3C(=NH)OC(CH3)3
CAS Number:
98946-18-0
Molecular Weight:
218.51
Beilstein:
1770049
MDL number:
MFCD00077410
UNSPSC 코드:
12352100
PubChem Substance ID:
24862454
NACRES:
NA.22

Quality Level

200

분석

96%

refractive index

n20/D 1.456 (lit.)

bp

65 °C/11 mmHg (lit.)

mp

21 °C (lit.)

density

1.221 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

CC(C)(C)OC(=N)C(Cl)(Cl)Cl

InChI

1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3

InChI key

CQXDYHPBXDZWBA-UHFFFAOYSA-N

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관련 카테고리

애플리케이션

tert-Butyl 2,2,2-trichloroacetimidate may be used in the synthesis of N-α-Fmoc-phospho(1-nitrophenylethyl-2-cyanoethyl)-L-serine, caged building block. It may be used in the conversion of alcohols and carboxylic acids to their respective ethers and esters.

픽토그램

FlameExclamation mark
GHS02,GHS07

신호어

Warning

유해 및 위험 성명서

H226,H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

131.0 °F - closed cup

Flash Point (°C)

55 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Journal of the Chemical Society. Perkin Transactions 1, 2247-2247 (1985)
Deborah M Rothman et al.
The Journal of organic chemistry, 68(17), 6795-6798 (2003-08-16)
Three 1-(2-nitrophenyl)ethyl-caged phospho-amino acids have been synthesized for use in standard N(alpha)-fluorenylmethoxycarbonyl-based solid-phase peptide synthesis (SPPS). The most common naturally occurring phospho-amino acids, serine, threonine, and tyrosine, were prepared as protected caged building blocks by modification with a unique phosphitylating
Tetrahedron Letters, 29, 2483-2483 (1988)
Maiyun Yang et al.
Nature communications, 5, 4981-4981 (2014-09-23)
Bioorthogonal reactions, especially the Cu(I)-catalysed azide-alkyne cycloaddition, have revolutionized our ability to label and manipulate biomolecules under living conditions. The cytotoxicity of Cu(I) ions, however, has hindered the application of this reaction in the internal space of living cells. By
Brett J Roberts et al.
Journal of cell science, 127(Pt 17), 3782-3793 (2014-07-09)
Desmosomes are prominent adhesive junctions found in various epithelial tissues. The cytoplasmic domains of desmosomal cadherins interact with a host of desmosomal plaque proteins, including plakophilins, plakoglobin and desmoplakin, which, in turn, recruit the intermediate filament cytoskeleton to sites of

문서

Trichloroacetimidate Reagents

Trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.

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