376159

(Trimethylsilyl)methyl isocyanide

97%

• 동의어(들): (Isocyanomethyl)trimethylsilane
• Linear Formula: (CH₃)₃SiCH₂NC
• CAS Number: 30718-17-3
• Molecular Weight: 113.23
• Beilstein: 3930556
• MDL number: MFCD00043056
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24863423
• NACRES: NA.22

속성

• 분석: 97%
• 형태: liquid
• refractive index: n20/D 1.416 (lit.)
• bp: 52-53 °C/35 mmHg (lit.)
• density: 0.803 g/mL at 25 °C (lit.)
• 저장 온도: −20°C
• SMILES string: C[Si](C)(C)C[N+]#[C-]
• InChI: 1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
• InChI key: OLSTVZKPVGMQKB-UHFFFAOYSA-N

설명

일반 설명

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η²-formaldehyde)zirconocene complex is reported to yield insertion products.

애플리케이션

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

안전성 정보

• 픽토그램: GHS02,GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H225,H301 + H311 + H331
• 예방조치 성명서: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): <59.0 °F - closed cup
• Flash Point (°C): < 15 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter