39410
4-(Dimethylamino)pyridine, polymer-bound
extent of labeling: ~3.0 mmol/g "DMAP" loading, matrix crosslinked with 2% DVB
동의어(들):
4-(Dimethylamino)pyridine on Polystyrene, DMAP on PS, polymer bound DMAP
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C8H8
CAS Number:
Molecular Weight:
104.15
MDL number:
UNSPSC 코드:
12352128
PubChem Substance ID:
NACRES:
NA.22
추천 제품
반응 적합성
reaction type: solution phase peptide synthesis
라벨링 범위
~3.0 mmol/g "DMAP" loading
Matrix
crosslinked with 2% DVB
음이온 미량물
chloride (Cl-): ≤5000 mg/kg
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일반 설명
Polymer-bound 4-(dimethylamino)pyridine is used for improved derivatization of chiral and achiral aliphatic amines, amino alcohols and amino acids.
애플리케이션
Polymer-bound 4-(dimethylamino)pyridine is used as a supported base in the Michael addition and nitrous acid elimination process step involved in the synthesis of thiophene-2-carboxylates using β-nitroacrylates as starting materials, under a general and efficient continuous flow-based protocol. It also serves as a supported catalyst in the preparation of ω-nitro esters starting from cyclic 2-nitro ketones under solid heterogeneous catalysis.(5)
기타 정보
Polymer supported, recyclable acylation catalyst
신호어
Warning
유해 및 위험 성명서
예방조치 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
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시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
$\beta$-Nitroacrylates as Starting Materials of Thiophene-2-Carboxylates Under Continuous Flow Conditions
Chiurchiu E, et al.
Advanced Synthesis & Catalysis, 361(9), 2042-2047 (2019)
A new, low impact and efficient synthesis of $\omega$-nitro esters under solid heterogeneous catalysis
Chiurchiu E, et al.
Green Chemistry, 19(20), 4956-4960 (2017)
$\beta$-Nitroacrylates as Starting Materials of Thiophene-2-Carboxylates Under Continuous Flow Conditions
Chiurchiu E, et al.
advanced synthesis and catalysis, 361(9), 2042-2047 (2019)
Szu-Yuan Chou et al.
Scientific reports, 10(1), 18519-18519 (2020-10-30)
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Bulletin of the Chemical Society of Japan, 54, 631-631 (1981)
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