411124

Chlorodicyclohexylborane solution

1 M in hexanes

• 동의어(들): Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
• Linear Formula: (C₆H₁₁)₂BCl
• CAS Number: 36140-19-9
• Molecular Weight: 212.57
• Beilstein: 3233942
• MDL number: MFCD00191906
• UNSPSC 코드: 12352106
• PubChem Substance ID: 24865728
• NACRES: NA.22

속성

• 양식: liquid
• Quality Level: 100
• 반응 적합성: reagent type: reductant
• 농도: 1 M in hexanes
• bp: 68-69 °C
• density: 0.752 g/mL at 25 °C
• SMILES string: ClB(C1CCCCC1)C2CCCCC2
• InChI: 1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
• InChI key: PBBOKJIYEZCTEH-UHFFFAOYSA-N

설명

애플리케이션

Reactant for:

• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H225,H250,H304,H314,H336,H361f,H372,H411
• 예방조치 성명서: P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3
• 표적 기관: Central nervous system, Nervous system
• Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• Flash Point (°F): 10.4 °F - closed cup
• Flash Point (°C): -12 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter