429007

1-Propynylmagnesium bromide solution

0.5 M in THF

• 동의어(들): 1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium
• Linear Formula: CH₃C≡CMgBr
• CAS Number: 16466-97-0
• Molecular Weight: 143.26
• Beilstein: 3929146
• MDL number: MFCD00216588
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24866829
• NACRES: NA.22

속성

• Quality Level: 200
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 0.5 M in THF
• bp: 65-67 °C
• density: 0.941 g/mL at 25 °C
• 저장 온도: 2-8°C
• SMILES string: CC#C[Mg]Br
• InChI: 1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
• InChI key: YVJBCTFVENNIOV-UHFFFAOYSA-M

설명

일반 설명

1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.

애플리케이션

Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H261,H302,H314,H335,H336,H351
• 예방조치 성명서: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): 30.2 °F - closed cup
• Flash Point (°C): -1 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter