419613
2-Methyl-1-propenylmagnesium bromide solution
0.5 M in THF
동의어(들):
(2-Methylpropenyl)magnesium bromide, 2,2-Dimethylvinylmagnesium bromide, Isobutenylmagnesium bromide
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모든 사진(1)
About This Item
Linear Formula:
(CH3)2C=CHMgBr
CAS Number:
Molecular Weight:
159.31
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
반응 적합성
reaction type: Grignard Reaction
농도
0.5 M in THF
density
0.952 g/mL at 25 °C
SMILES string
C\C(C)=C\[Mg]Br
InChI
1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChI key
BKVIQODYSREJQH-UHFFFAOYSA-M
일반 설명
2-Methyl-1-propenylmagnesiumbromide is a heterocyclic organic compound. It is used as a Grignard reagent in chemical synthesis.
애플리케이션
Used in a study of a palladium-catalyzed coupling with aryl tosylates.
Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point (°F)
5.0 °F - closed cup
Flash Point (°C)
-15 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Jean-Damien Charrier et al.
Organic & biomolecular chemistry, 2(5), 797-802 (2004-02-27)
The fluorinated amino acid, (2S,3S)-3'-fluoroisoleucine 3, has been synthesised by a route involving stereoselective cuprate or photochemical addition to the compound 4, derived in turn from (2S)-pyroglutamic acid. This provides a reporter group for the hydrophobic amino acid (2S)-isoleucine for
Michael E Limmert et al.
The Journal of organic chemistry, 70(23), 9364-9370 (2005-11-05)
[Reaction: see text]. Aryl and alkenyl tosylates are easily prepared, inexpensive and, thus, attractive for transition-metal-catalyzed couplings, but their reactivity is low. We report examples of mild, palladium-catalyzed coupling of aryl, alkenyl, and alkyl Grignard reagents with aryl and alkenyl
Enantioselective Oxy-Heck--Matsuda Arylations: Expeditious Synthesis of Dihydrobenzofuran Systems and Total Synthesis of the Neolignan (-)-Conocarpan
Silva AR, et al.
advanced synthesis and catalysis, 360(2), 346-365 (2018)
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