추천 제품
반응 적합성
reaction type: Grignard Reaction
Quality Level
농도
0.5 M in THF
bp
65-67 °C
density
0.915 g/mL at 25 °C
SMILES string
CC(=C)C[Mg]Cl
InChI
1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1
InChI key
BJVFGWYBOLMUEM-UHFFFAOYSA-M
애플리케이션
2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.
포장
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
법적 정보
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point (°F)
-5.8 °F - closed cup
Flash Point (°C)
-21 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
The total synthesis of (−)-aplysin via a lithiation?borylation?propenylation sequence.
Tetrahedron, 68(37), 7598-7604 (2012)
Allyldicyclopentadienyltitanium (III) and (DI) methylallyl homologues.
Journal of Organometallic Chemistry, 8(1), 115-128 (1967)
?Classical carbonyl reactivity enables a short synthesis of the core structure of acutumine?
Tetrahedron, 63(28), 6446-6453 (2007)
Proceedings of the National Academy of Sciences of the United States of America, 95(26), 15351-15355 (1998-12-23)
The synthesis of novel fluorogenic retro-aldol substrates for aldolase antibody 38C2 is described. These substrates are efficiently and specifically processed by antibody aldolases but not by natural cellular enzymes. Together, the fluorogenic substrates and antibody aldolases provide reporter gene systems
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