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Merck
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주요 문서

429414

Sigma-Aldrich

Indium(III) chloride

anhydrous, powder, ≥99.999% trace metals basis

동의어(들):

Trichloroindigane, Indium trichloride

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About This Item

Linear Formula:
InCl3
CAS Number:
Molecular Weight:
221.18
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23

Grade

anhydrous

Quality Level

분석

≥99.999% trace metals basis

형태

powder

반응 적합성

reagent type: catalyst
core: indium

불순물

<100 ppm H2O

density

3.46 g/mL at 25 °C (lit.)

SMILES string

Cl[In](Cl)Cl

InChI

1S/3ClH.In/h3*1H;/q;;;+3/p-3

InChI key

PSCMQHVBLHHWTO-UHFFFAOYSA-K

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일반 설명

InCl3 is an efficient water-stable Lewis acid catalyst used in many organic transformations. It is moderately toxic and shows high tolerance to most of the oxygen and nitrogen containing functional groups. Owing to its optoelectronic properties it is also used to prepare many semiconductor materials.

애플리케이션

Indium(lll) chloride can be used as a catalyst to synthesize:
  • Indolylindolines through self-addition of indoles.
  • Vinyl indoles from unfunctionalized indoles and vinyl azides.
  • Variety of cycloadducts through the reaction of olefinic acetals with isoprene and cyclopentadiene.
  • N-tosylimines through a condensation reaction of aldehydes with p-toluenesulfonamide.

픽토그램

Health hazardCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

표적 기관

Lungs

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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시험 성적서(COA)

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문서 라이브러리 방문

Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride
Wieslaw Gawel and Tomasz Kloc and Igor Mucha
Inorganica chimica acta, 495, 118991-118991 (2019)
Efficient and convenient preparation of N-tosylimines catalyzed by indium trichloride
Gui Sheng Deng et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(5), 511-514 (2011)
First indium trichloride catalyzed self-addition of indoles: One pot synthesis of indolylindolines
Bikash Pal, et al.
Catalysis Communications, 6(11), 711-715 (2005)
Indium trichloride: a useful catalyst for ionic Diels?Alder reactions
B.Gopal Reddy, et al.
Tetrahedron Letters, 41(52), 10333-10336 (2000)
Indium(III) Catalyzed Reactions of Vinyl Azides and Indoles
More, Atul A. and Szpilman, Alex M.
Organic Letters, 22(10), 3759-3764 (2020)

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