추천 제품
Quality Level
분석
≥98.0% (AT)
반응 적합성
reagent type: oxidant
mp
233-235 °C (subl.) (lit.)
작용기
iodo
SMILES string
[Cl-].[I+](c1ccccc1)c2ccccc2
InChI
1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
InChI key
RSJLWBUYLGJOBD-UHFFFAOYSA-M
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애플리케이션
Reactant for:
- Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
- Synthesis of acetylenic arylselenides
- Sonogashira coupling reactions for the preparation of aryl alkynes
- C-H functionalization for synthesis of (arylmethylene)oxindoles
- Arylation of anilines
- Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
- Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators
기타 정보
Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
The Journal of Organic Chemistry, 52, 4115-4115 (1987)
The Journal of Organic Chemistry, 4117-4117 (1987)
Synthesis, 723-723 (1988)
Journal of the American Chemical Society, 133(35), 13778-13781 (2011-08-19)
A new strategy for the catalytic enantioselective α-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied
Chemical communications (Cambridge, England), 48(72), 9089-9091 (2012-08-03)
A novel metal-free direct arylation of unbiased arenes with diaryliodonium triflates in a process where the use of solvents and additives is not required has been established.
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