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Merck
모든 사진(1)

주요 문서

44570

Sigma-Aldrich

Dowtherm® A

eutectic mixture of 26.5% diphenyl + 73.5% diphenyl oxide

동의어(들):

Diphyl

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About This Item

MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

refractive index

n20/D 1.590

mp

12-14 °C (lit.)

작용기

phenoxy
phenyl

SMILES string

c1ccc(cc1)-c2ccccc2.O(c3ccccc3)c4ccccc4

InChI

1S/C12H10O.C12H10/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H;1-10H

InChI key

MHCVCKDNQYMGEX-UHFFFAOYSA-N

일반 설명

Dowtherm® A is a thermally stable organic heat transfer fluid composed of a eutectic mixture of highly stable compounds, biphenyl, and diphenyl oxide. Dowtherm® A is suitable for high-temperature heat transfer applications up to 400 °C. This fluid can be used in both liquid and vapor phase systems.

애플리케이션

Dowtherm® A can be used as a high boiling solvent in cyclization reactions. For example, it is used to synthesize:      
  • 1-Hydroxy-5-methoxy-1,2-dihydrobenzo[f][2,7]naphthyridines from 2-chloro-3-formyl quinolines.     
  • Isoindolinone derivatives via intramolecular Diels–Alder cycloaddition reactions of substituted pyridazines.
  • Phosphorylated azaheterocycles from 2-diethoxyphosphoryl-3-methoxyacrylate via intramolecular cyclizations under thermal conditions.

법적 정보

DOWTHERM is a registered trademark of The Dow Chemical Company or an affiliated company of Dow

픽토그램

Exclamation markEnvironment

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Rolf Winter et al.
Experimental parasitology, 127(2), 545-551 (2010-11-03)
Our prior work on tricyclic acridones combined with a desire to minimize the tricyclic system led to an interest in antimalarial quinolones and a reexamination of endochin, an experimental antimalarial from the 1940's. In the present article, we show that
F M Moh et al.
Journal of AOAC International, 82(4), 893-896 (1999-08-13)
A rapid and direct liquid chromatographic (LC) technique is described for the determination of a eutectic mixture of diphenyl oxide and biphenyl such as Dowtherm A thermal heating fluid (THF) in oleochemicals and palm olein. Analysis is performed with an
Synthesis of isoindolinones via inverse-electron demand Diels-Alder cycloadditions
Huntley RJ, et al.
Tetrahedron Letters, 55(14), 2286-2289 (2014)
Enhancement of heat transport in thermosyphon air preheater at high temperature with binary working fluid: A case study of TEG-water.
Nuntaphan A, et al.
Applied Thermal Engineering, 22(3), 251-266 (2002)
Hongwei Yao et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 20(1), 5-9 (2003-12-26)
To study injury of liver and kidney among the workers exposed to terephthalic acid(TPA), ethylene glycol(EG) and(or) dowtherm A(DOW), and research for early biological monitoring indexes. By using the method of occupational epidemiology, an investigation of industrial hygiene in a

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